Isolation of a new two-dimensional honeycomb carbonato-bridged copper(II) complex exhibiting long-range ferromagnetic ordering

Arpi Majumder, Chirantan Roy Choudhury, Samiran Mitra, Georgina M. Rosair, M. Salah El Fallah, Joan Ribas

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Atmospheric CO2 fixation by an aqueous solution containing Cu(ClO4)2·6H2O and 4-aminopyridine (4-apy) yields a novel example of a two-dimensional µ3-CO 3 bridged copper(II) complex {[Cu(4-apy)2] 33-CO3)2(ClO4) 2·1/2CH3OH}n 1 that has been characterized by IR, UV and X-ray crystallography; preliminary magnetic measurements show that complex 1 exhibits long-range ordered ferromagnetic coupling. © The Royal Society of Chemistry 2005.

Original languageEnglish
Pages (from-to)2158-2160
Number of pages3
JournalChemical Communications
Issue number16
DOIs
Publication statusPublished - 28 Apr 2005

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