Isolation of a new two-dimensional honeycomb carbonato-bridged copper(II) complex exhibiting long-range ferromagnetic ordering

Arpi Majumder; Chirantan Roy Choudhury; Samiran Mitra; Georgina M. Rosair; M. Salah El Fallah; Joan Ribas

doi:10.1039/b417019a

Isolation of a new two-dimensional honeycomb carbonato-bridged copper(II) complex exhibiting long-range ferromagnetic ordering

Arpi Majumder, Chirantan Roy Choudhury, Samiran Mitra, Georgina M. Rosair, M. Salah El Fallah, Joan Ribas

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Atmospheric CO₂ fixation by an aqueous solution containing Cu(ClO₄)₂·6H₂O and 4-aminopyridine (4-apy) yields a novel example of a two-dimensional µ₃-CO ₃ bridged copper(II) complex {[Cu(4-apy)₂] ₃(µ₃-CO₃)2(ClO₄) ₂·1/2CH₃OH}_n 1 that has been characterized by IR, UV and X-ray crystallography; preliminary magnetic measurements show that complex 1 exhibits long-range ordered ferromagnetic coupling. © The Royal Society of Chemistry 2005.

Original language	English
Pages (from-to)	2158-2160
Number of pages	3
Journal	Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/b417019a
Publication status	Published - 28 Apr 2005

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title = "Isolation of a new two-dimensional honeycomb carbonato-bridged copper(II) complex exhibiting long-range ferromagnetic ordering",

abstract = "Atmospheric CO2 fixation by an aqueous solution containing Cu(ClO4)2·6H2O and 4-aminopyridine (4-apy) yields a novel example of a two-dimensional µ3-CO 3 bridged copper(II) complex {[Cu(4-apy)2] 3(µ3-CO3)2(ClO4) 2·1/2CH3OH}n 1 that has been characterized by IR, UV and X-ray crystallography; preliminary magnetic measurements show that complex 1 exhibits long-range ordered ferromagnetic coupling. {\textcopyright} The Royal Society of Chemistry 2005.",

author = "Arpi Majumder and Choudhury, {Chirantan Roy} and Samiran Mitra and Rosair, {Georgina M.} and {El Fallah}, {M. Salah} and Joan Ribas",

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doi = "10.1039/b417019a",

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AU - Majumder, Arpi

AU - Choudhury, Chirantan Roy

AU - Mitra, Samiran

AU - Rosair, Georgina M.

AU - El Fallah, M. Salah

AU - Ribas, Joan

PY - 2005/4/28

Y1 - 2005/4/28

N2 - Atmospheric CO2 fixation by an aqueous solution containing Cu(ClO4)2·6H2O and 4-aminopyridine (4-apy) yields a novel example of a two-dimensional µ3-CO 3 bridged copper(II) complex {[Cu(4-apy)2] 3(µ3-CO3)2(ClO4) 2·1/2CH3OH}n 1 that has been characterized by IR, UV and X-ray crystallography; preliminary magnetic measurements show that complex 1 exhibits long-range ordered ferromagnetic coupling. © The Royal Society of Chemistry 2005.

AB - Atmospheric CO2 fixation by an aqueous solution containing Cu(ClO4)2·6H2O and 4-aminopyridine (4-apy) yields a novel example of a two-dimensional µ3-CO 3 bridged copper(II) complex {[Cu(4-apy)2] 3(µ3-CO3)2(ClO4) 2·1/2CH3OH}n 1 that has been characterized by IR, UV and X-ray crystallography; preliminary magnetic measurements show that complex 1 exhibits long-range ordered ferromagnetic coupling. © The Royal Society of Chemistry 2005.

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EP - 2160

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

Isolation of a new two-dimensional honeycomb carbonato-bridged copper(II) complex exhibiting long-range ferromagnetic ordering

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