Iron(0) and ruthenium(0) complexes of dinitrogen

Leslie D. Field, Ruth W. Guest, Khuong Q. Vuong, Scott J. Dalgarno, Paul Jensen

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Abstract

The synthesis of a series of iron and ruthenium complexes with the new ligand PPi3 (1) P(CH2CH2P iPr2)3 is described. The iron(0) and ruthenium(0) dinitrogen complexes Fe(N2)(PPi3) (4) and Ru(N2)(PPi3) (5) were synthesized by treatment of the iron(ll) and ruthenium(ll) cationic species [FeCI(PP i3)]+ (2) and [RuCI(PPi3)]+ (3) with potassium graphite under a nitrogen atmosphere. The cationic dinitrogen species [Fe(N2)H(PP i3)]+ (6) and [Ru(N2)H(PP i3)]+ (7) were prepared by treatment of 4 and 5, respectively, with 1 equiv of a weak organic acid. Complexes 2 · [BPh4], 3-[BPh4], 4, 5, and 6-[BF4] were characterized by X-ray crystallography. The structural characterization of 5 is the first report for a ruthenium(0) dinitrogen complex. © 2009 American Chemical Society.

Original languageEnglish
Pages (from-to)2246-2253
Number of pages8
JournalInorganic Chemistry
Volume48
Issue number5
DOIs
Publication statusPublished - 2 Mar 2009

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    Field, L. D., Guest, R. W., Vuong, K. Q., Dalgarno, S. J., & Jensen, P. (2009). Iron(0) and ruthenium(0) complexes of dinitrogen. Inorganic Chemistry, 48(5), 2246-2253. https://doi.org/10.1021/ic8019827