Ionothermal synthesis of the mixed-anion material, Ba3Cl4CO3

Patricia Leyva-Bailen; Paz Vaqueiro; Anthony V. Powell

doi:10.1016/j.jssc.2009.06.019

Ionothermal synthesis of the mixed-anion material, Ba₃Cl₄CO₃

Patricia Leyva-Bailen, Paz Vaqueiro, Anthony V. Powell

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

A low-temperature ionothermal method for the facile synthesis of the halide carbonate, Ba₃Cl₄CO₃, in single-crystalline form has been developed. This has enabled the first determination of the crystal structure of this material to be carried out. Analysis of single-crystal X-ray diffraction data indicates that barium chloride carbonate crystallises in the orthorhombic space group Pnma (Z=4), with a=8.4074(11), b=9.5886(12), c=12.4833(15) Å (R_w=0.0392). It exhibits a complex structure in which a three-dimensional network is formed from cross-linking of chains of anion-centred octahedra that share faces. © 2009 Elsevier Inc. All rights reserved.

Original language	English
Pages (from-to)	2333-2337
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	182
Issue number	9
DOIs	https://doi.org/10.1016/j.jssc.2009.06.019
Publication status	Published - Sept 2009

Keywords

Crystal structure
Halide carbonate
Ionothermal synthesis
Mixed-anion compound

Access to Document

10.1016/j.jssc.2009.06.019

Cite this

@article{e3078378fe0043e7acd703722e7dff3c,

title = "Ionothermal synthesis of the mixed-anion material, Ba3Cl4CO3",

abstract = "A low-temperature ionothermal method for the facile synthesis of the halide carbonate, Ba3Cl4CO3, in single-crystalline form has been developed. This has enabled the first determination of the crystal structure of this material to be carried out. Analysis of single-crystal X-ray diffraction data indicates that barium chloride carbonate crystallises in the orthorhombic space group Pnma (Z=4), with a=8.4074(11), b=9.5886(12), c=12.4833(15) {\AA} (Rw=0.0392). It exhibits a complex structure in which a three-dimensional network is formed from cross-linking of chains of anion-centred octahedra that share faces. {\textcopyright} 2009 Elsevier Inc. All rights reserved.",

keywords = "Crystal structure, Halide carbonate, Ionothermal synthesis, Mixed-anion compound",

author = "Patricia Leyva-Bailen and Paz Vaqueiro and Powell, {Anthony V.}",

year = "2009",

month = sep,

doi = "10.1016/j.jssc.2009.06.019",

language = "English",

volume = "182",

pages = "2333--2337",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "9",

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TY - JOUR

T1 - Ionothermal synthesis of the mixed-anion material, Ba3Cl4CO3

AU - Leyva-Bailen, Patricia

AU - Vaqueiro, Paz

AU - Powell, Anthony V.

PY - 2009/9

Y1 - 2009/9

N2 - A low-temperature ionothermal method for the facile synthesis of the halide carbonate, Ba3Cl4CO3, in single-crystalline form has been developed. This has enabled the first determination of the crystal structure of this material to be carried out. Analysis of single-crystal X-ray diffraction data indicates that barium chloride carbonate crystallises in the orthorhombic space group Pnma (Z=4), with a=8.4074(11), b=9.5886(12), c=12.4833(15) Å (Rw=0.0392). It exhibits a complex structure in which a three-dimensional network is formed from cross-linking of chains of anion-centred octahedra that share faces. © 2009 Elsevier Inc. All rights reserved.

AB - A low-temperature ionothermal method for the facile synthesis of the halide carbonate, Ba3Cl4CO3, in single-crystalline form has been developed. This has enabled the first determination of the crystal structure of this material to be carried out. Analysis of single-crystal X-ray diffraction data indicates that barium chloride carbonate crystallises in the orthorhombic space group Pnma (Z=4), with a=8.4074(11), b=9.5886(12), c=12.4833(15) Å (Rw=0.0392). It exhibits a complex structure in which a three-dimensional network is formed from cross-linking of chains of anion-centred octahedra that share faces. © 2009 Elsevier Inc. All rights reserved.

KW - Crystal structure

KW - Halide carbonate

KW - Ionothermal synthesis

KW - Mixed-anion compound

U2 - 10.1016/j.jssc.2009.06.019

DO - 10.1016/j.jssc.2009.06.019

M3 - Article

SN - 0022-4596

VL - 182

SP - 2333

EP - 2337

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 9