Interplay of Metal-Atom Ordering, Fermi Level Tuning, and Thermoelectric Properties in Cobalt Shandites Co3M2S2 (M = Sn, In)

Jack Corps, Paz Vaqueiro, Alex Aziz, Ricardo Grau-Crespo, Winfried Kockelmann, Jean-Claude Jumas, Anthony Vivian Powell

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

A combination of structural, physical, and computational techniques including powder X-ray and neutron diffraction, SQUID magnetometry, electrical and thermal transport measurements, DFT calculations, and Sn-119 Mossbauer and X-ray photoelectron spectroscopies has been applied to Co3Sn2-xInxS2 (0

Original languageEnglish
Pages (from-to)3946-3956
Number of pages11
JournalChemistry of Materials
Volume27
Issue number11
DOIs
Publication statusPublished - 9 Jun 2015

Keywords

  • ELECTRON-BINDING ENERGIES
  • WAVE BASIS-SET
  • NEUTRON-DIFFRACTION
  • CRYSTAL-STRUCTURE
  • THIN-FILMS
  • SULFUR
  • TIN
  • ENVIRONMENTS
  • PENTLANDITE
  • EFFICIENCY

Cite this

Corps, J., Vaqueiro, P., Aziz, A., Grau-Crespo, R., Kockelmann, W., Jumas, J-C., & Powell, A. V. (2015). Interplay of Metal-Atom Ordering, Fermi Level Tuning, and Thermoelectric Properties in Cobalt Shandites Co3M2S2 (M = Sn, In). Chemistry of Materials, 27(11), 3946-3956. https://doi.org/10.1021/acs.chemmater.5b00801