Interaction matrices for the d4 configuration

H. U. Rahman

Research output: Contribution to journalArticlepeer-review


Combined intro- and inter-configurational interaction matrices for all the states of t24 and t23e configurations are calculated in a strong cubic field scheme. They include electrostatic, spin-orbit and cubic field interactions. The matrices are used to analyse the absorption spectrum of Cs2ZrCl6:Os4+. © 2003 Elsevier Science B.V. All rights reserved.

Original languageEnglish
Pages (from-to)82-87
Number of pages6
JournalPhysica B: Condensed Matter
Issue number1-2
Publication statusPublished - 2003


  • Atomic spectra
  • Crystal and ligand fields
  • Level splitting and interactions


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