Infrared dielectric dispersion of ZnGeP2 and CdGeP2

Alan Miller, G. D. Holah, W. C. Clark

Research output: Contribution to journalArticle

Abstract

The polarised i.r. reflectivity spectra of single crystals of the non-linear chalcopyrite materials ZnGeP2 and CdGeP2 have been measured over the spectral range 40-700 cm-1. Analysis of the spectra using classical dispersion theory and the Kramers-Krönig technique has yielded, in each material, five modes with frequencies between 80 and 385 cm-1 with the polarisation perpendicular to the optic axis. Parallel to the optic axis, two modes have been observed with frequencies between 300 and 400 cm-1. The phonon dispersion curves of the isoelectronic analogue GaP have been used, together with a group theoretical analysis, to assign specific atomic displacements to the observed modes. © 1974.

Original languageEnglish
Pages (from-to)685-693
Number of pages9
JournalJournal of Physics and Chemistry of Solids
Volume35
Issue number6
DOIs
Publication statusPublished - 1974

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optics
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single crystals
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Miller, Alan ; Holah, G. D. ; Clark, W. C. / Infrared dielectric dispersion of ZnGeP2 and CdGeP2. In: Journal of Physics and Chemistry of Solids. 1974 ; Vol. 35, No. 6. pp. 685-693.
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Infrared dielectric dispersion of ZnGeP2 and CdGeP2. / Miller, Alan; Holah, G. D.; Clark, W. C.

In: Journal of Physics and Chemistry of Solids, Vol. 35, No. 6, 1974, p. 685-693.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Infrared dielectric dispersion of ZnGeP2 and CdGeP2

AU - Miller, Alan

AU - Holah, G. D.

AU - Clark, W. C.

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