Influencing the orientation of jahn-teller axes in butterfly-like Mn-4(III) clusters

Ross McLellan; Maria A. Palacios; Euan K. Brechin; Scott J. Dalgarno

doi:10.1002/cplu.201400031

Influencing the orientation of jahn-teller axes in butterfly-like Mn-4(III) clusters

Ross McLellan
, Maria A. Palacios
, Euan K. Brechin^*
, Scott J. Dalgarno

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A bis-phenolate that has structural similarities to both calix[4]arene and the oxacalix[n]arenes provides access to a butterfly-like Mn-4 cluster in which all metals are in the oxidation state+3. Specific properties of this ligand, in comparison to others in the literature, offer a route to influencing the orientation of the Jahn-Teller axes within this cluster motif, which possesses a rare oxidation state arrangement.

Original language	English
Pages (from-to)	667-670
Number of pages	4
Journal	ChemPlusChem
Volume	79
Issue number	5
DOIs	https://doi.org/10.1002/cplu.201400031
Publication status	Published - May 2014

Keywords

calixarenes
cluster compounds
coordination chemistry
magnetism
manganese
SINGLE-MOLECULE MAGNETS
MANGANESE(III) COMPLEXES
CRYSTAL-STRUCTURES
BIS-PHENOLATE
TETRANUCLEAR

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title = "Influencing the orientation of jahn-teller axes in butterfly-like Mn-4(III) clusters",

abstract = "A bis-phenolate that has structural similarities to both calix[4]arene and the oxacalix[n]arenes provides access to a butterfly-like Mn-4 cluster in which all metals are in the oxidation state+3. Specific properties of this ligand, in comparison to others in the literature, offer a route to influencing the orientation of the Jahn-Teller axes within this cluster motif, which possesses a rare oxidation state arrangement.",

keywords = "calixarenes, cluster compounds, coordination chemistry, magnetism, manganese, SINGLE-MOLECULE MAGNETS, MANGANESE(III) COMPLEXES, CRYSTAL-STRUCTURES, BIS-PHENOLATE, TETRANUCLEAR",

author = "Ross McLellan and Palacios, \{Maria A.\} and Brechin, \{Euan K.\} and Dalgarno, \{Scott J.\}",

year = "2014",

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language = "English",

volume = "79",

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T1 - Influencing the orientation of jahn-teller axes in butterfly-like Mn-4(III) clusters

AU - McLellan, Ross

AU - Palacios, Maria A.

AU - Brechin, Euan K.

AU - Dalgarno, Scott J.

PY - 2014/5

Y1 - 2014/5

N2 - A bis-phenolate that has structural similarities to both calix[4]arene and the oxacalix[n]arenes provides access to a butterfly-like Mn-4 cluster in which all metals are in the oxidation state+3. Specific properties of this ligand, in comparison to others in the literature, offer a route to influencing the orientation of the Jahn-Teller axes within this cluster motif, which possesses a rare oxidation state arrangement.

AB - A bis-phenolate that has structural similarities to both calix[4]arene and the oxacalix[n]arenes provides access to a butterfly-like Mn-4 cluster in which all metals are in the oxidation state+3. Specific properties of this ligand, in comparison to others in the literature, offer a route to influencing the orientation of the Jahn-Teller axes within this cluster motif, which possesses a rare oxidation state arrangement.

KW - calixarenes

KW - cluster compounds

KW - coordination chemistry

KW - magnetism

KW - manganese

KW - SINGLE-MOLECULE MAGNETS

KW - MANGANESE(III) COMPLEXES

KW - CRYSTAL-STRUCTURES

KW - BIS-PHENOLATE

KW - TETRANUCLEAR

U2 - 10.1002/cplu.201400031

DO - 10.1002/cplu.201400031

M3 - Article

SN - 2192-6506

VL - 79

SP - 667

EP - 670

JO - ChemPlusChem

JF - ChemPlusChem

IS - 5

ER -

Influencing the orientation of jahn-teller axes in butterfly-like Mn-4(III) clusters

Abstract

Keywords

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