Inclusion of Thiazyl Radicals in Porous Crystalline Materials

Storm V. Potts, Leonard J. Barbour, Delia A. Haynes, Jeremy M. Rawson, Gareth O. Lloyd

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

The incorporation of benzodithiazolyl (BDTA) and methylbenzodithiazolyl (MBDTA) radicals into porous hybrid frameworks via gas phase diffusion revealed that inclusion appeared selective for the MIL53(Al) framework against a range of other potential hosts. Both PXRD and EPR studies are consistent with retention of a pi*-pi* dimer motif for BDTA in MIL53(Al)@BDTA whereas MBDTA in MIL53(Al)@MBDTA appears to be monomeric. The guests are readily released by the addition of solvent (CH(2)Cl(2)).

Original languageEnglish
Pages (from-to)12948-12951
Number of pages4
JournalJournal of the American Chemical Society
Volume133
Issue number33
DOIs
Publication statusPublished - 24 Aug 2011

Keywords

  • DITHIAZOLYL RADICALS
  • ZEOLITIC IMIDAZOLATE FRAMEWORKS
  • OLD MATERIALS
  • MAGNETIC-PROPERTIES
  • METAL-ORGANIC FRAMEWORK
  • POLYMORPHISM
  • ADSORPTION
  • MIL-53(AL)
  • DITHIADIAZOLYL
  • DISCRETE METALLOCYCLIC COMPLEX

Cite this

Potts, S. V., Barbour, L. J., Haynes, D. A., Rawson, J. M., & Lloyd, G. O. (2011). Inclusion of Thiazyl Radicals in Porous Crystalline Materials. Journal of the American Chemical Society, 133(33), 12948-12951. https://doi.org/10.1021/ja204548d