In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes

Joe C. Goodall; M. Arif Sajjad; Emily A. Thompson; Samuel J. Page; Adam M. Kerrigan; Huw T. Jenkins; Jason M. Lynam; Stuart A. Macgregor; Andrew S. Weller

doi:10.1039/d3cc03201a

In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes

Joe C. Goodall, M. Arif Sajjad, Emily A. Thompson, Samuel J. Page, Adam M. Kerrigan, Huw T. Jenkins^*, Jason M. Lynam^*, Stuart A. Macgregor^*, Andrew S. Weller^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

The group 7 complexes [M(κ³-2,6-(R₂PO)₂C₅H₃N)(CO)₂L][BAr^F₄] [M = Mn, R = iPr, L = THF; M = Re, R = tBu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BAr^F₄] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity.

Original language	English
Pages (from-to)	10749-10752
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	72
Early online date	7 Aug 2023
DOIs	https://doi.org/10.1039/d3cc03201a
Publication status	Published - 16 Sept 2023

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title = "In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes",

abstract = "The group 7 complexes [M(κ3-2,6-(R2PO)2C5H3N)(CO)2L][BArF4] [M = Mn, R = iPr, L = THF; M = Re, R = tBu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BArF4] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity.",

author = "Goodall, {Joe C.} and Sajjad, {M. Arif} and Thompson, {Emily A.} and Page, {Samuel J.} and Kerrigan, {Adam M.} and Jenkins, {Huw T.} and Lynam, {Jason M.} and Macgregor, {Stuart A.} and Weller, {Andrew S.}",

year = "2023",

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day = "16",

doi = "10.1039/d3cc03201a",

language = "English",

volume = "59",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes

AU - Goodall, Joe C.

AU - Sajjad, M. Arif

AU - Thompson, Emily A.

AU - Page, Samuel J.

AU - Kerrigan, Adam M.

AU - Jenkins, Huw T.

AU - Lynam, Jason M.

AU - Macgregor, Stuart A.

AU - Weller, Andrew S.

PY - 2023/9/16

Y1 - 2023/9/16

N2 - The group 7 complexes [M(κ3-2,6-(R2PO)2C5H3N)(CO)2L][BArF4] [M = Mn, R = iPr, L = THF; M = Re, R = tBu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BArF4] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity.

AB - The group 7 complexes [M(κ3-2,6-(R2PO)2C5H3N)(CO)2L][BArF4] [M = Mn, R = iPr, L = THF; M = Re, R = tBu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BArF4] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity.

UR - http://www.scopus.com/inward/record.url?scp=85169511025&partnerID=8YFLogxK

U2 - 10.1039/d3cc03201a

DO - 10.1039/d3cc03201a

M3 - Article

C2 - 37602809

SN - 1359-7345

VL - 59

SP - 10749

EP - 10752

JO - Chemical Communications

JF - Chemical Communications

IS - 72

ER -

In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes

Abstract

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