closo-Carbametallaboranes with Metal-Hydrogen Bonds from Direct Insertion into arachno-Carbaboranes:  The Molecular Structures of [2-H-2,2-(Et3P)2-1,6,2-C2CoB7H9] and[2-H-2,2-(Et3P)2-1,6,2-C2RhB7H9] and a Most Unusual Crystallographic Coincidence

Geoffrey K. Barker; Maria P. Garcia; Michael Green; F. Gordon A. Stone; Jean Marie Bassett; Alan J. Welch

doi:10.1039/C39810000653

closo-Carbametallaboranes with Metal-Hydrogen Bonds from Direct Insertion into arachno-Carbaboranes: The Molecular Structures of [2-H-2,2-(Et₃P)₂-1,6,2-C₂CoB₇H₉] and[2-H-2,2-(Et₃P)₂-1,6,2-C₂RhB₇H₉] and a Most Unusual Crystallographic Coincidence

Geoffrey K. Barker^*, Maria P. Garcia, Michael Green, F. Gordon A. Stone, Jean Marie Bassett, Alan J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The arachno-carbaborane 1,3-C₂B₇H₁₃ reacts with [Co(PEt₃)₄] and with [Rh(η-C₃H₅)(PEt₃)₂] to afford, respectively, [2-H-2,2-(Et₃P)₂-1,6,2-C₂CoB₇H₉] and [2-H-2,2-(Et₃P)₂-1,6,2-C ₂RhB₇H₉]; both structures have been established by X-ray diffraction studies, but, whilst they crystallise in nearly identical unit cells and the same space group, these species are not isostructural.

Original language	English
Pages (from-to)	653-655
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/C39810000653
Publication status	Published - 1981

ASJC Scopus subject areas

Molecular Medicine

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Barker, G. K., Garcia, M. P., Green, M., Stone, F. G. A., Bassett, J. M., & Welch, A. J. (1981). closo-Carbametallaboranes with Metal-Hydrogen Bonds from Direct Insertion into arachno-Carbaboranes: The Molecular Structures of [2-H-2,2-(Et₃P)₂-1,6,2-C₂CoB₇H₉] and[2-H-2,2-(Et₃P)₂-1,6,2-C₂RhB₇H₉] and a Most Unusual Crystallographic Coincidence. Journal of the Chemical Society, Chemical Communications, (13), 653-655. https://doi.org/10.1039/C39810000653

Barker, Geoffrey K. ; Garcia, Maria P. ; Green, Michael et al. / closo-Carbametallaboranes with Metal-Hydrogen Bonds from Direct Insertion into arachno-Carbaboranes: The Molecular Structures of [2-H-2,2-(Et₃P)₂-1,6,2-C₂CoB₇H₉] and[2-H-2,2-(Et₃P)₂-1,6,2-C₂RhB₇H₉] and a Most Unusual Crystallographic Coincidence. In: Journal of the Chemical Society, Chemical Communications. 1981 ; No. 13. pp. 653-655.

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title = "closo-Carbametallaboranes with Metal-Hydrogen Bonds from Direct Insertion into arachno-Carbaboranes: The Molecular Structures of [2-H-2,2-(Et3P)2-1,6,2-C2CoB7H9] and[2-H-2,2-(Et3P)2-1,6,2-C2RhB7H9] and a Most Unusual Crystallographic Coincidence",

abstract = "The arachno-carbaborane 1,3-C2B7H13 reacts with [Co(PEt3)4] and with [Rh(η-C3H5)(PEt3)2] to afford, respectively, [2-H-2,2-(Et3P)2-1,6,2-C2CoB7H9] and [2-H-2,2-(Et3P)2-1,6,2-C 2RhB7H9]; both structures have been established by X-ray diffraction studies, but, whilst they crystallise in nearly identical unit cells and the same space group, these species are not isostructural.",

author = "Barker, {Geoffrey K.} and Garcia, {Maria P.} and Michael Green and Stone, {F. Gordon A.} and Bassett, {Jean Marie} and Welch, {Alan J.}",

year = "1981",

doi = "10.1039/C39810000653",

language = "English",

pages = "653--655",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "13",

}

Barker, GK, Garcia, MP, Green, M, Stone, FGA, Bassett, JM & Welch, AJ 1981, 'closo-Carbametallaboranes with Metal-Hydrogen Bonds from Direct Insertion into arachno-Carbaboranes: The Molecular Structures of [2-H-2,2-(Et₃P)₂-1,6,2-C₂CoB₇H₉] and[2-H-2,2-(Et₃P)₂-1,6,2-C₂RhB₇H₉] and a Most Unusual Crystallographic Coincidence', Journal of the Chemical Society, Chemical Communications, no. 13, pp. 653-655. https://doi.org/10.1039/C39810000653

closo-Carbametallaboranes with Metal-Hydrogen Bonds from Direct Insertion into arachno-Carbaboranes: The Molecular Structures of [2-H-2,2-(Et₃P)₂-1,6,2-C₂CoB₇H₉] and[2-H-2,2-(Et₃P)₂-1,6,2-C₂RhB₇H₉] and a Most Unusual Crystallographic Coincidence. / Barker, Geoffrey K.; Garcia, Maria P.; Green, Michael et al.
In: Journal of the Chemical Society, Chemical Communications, No. 13, 1981, p. 653-655.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - closo-Carbametallaboranes with Metal-Hydrogen Bonds from Direct Insertion into arachno-Carbaboranes: The Molecular Structures of [2-H-2,2-(Et3P)2-1,6,2-C2CoB7H9] and[2-H-2,2-(Et3P)2-1,6,2-C2RhB7H9] and a Most Unusual Crystallographic Coincidence

AU - Barker, Geoffrey K.

AU - Garcia, Maria P.

AU - Green, Michael

AU - Stone, F. Gordon A.

AU - Bassett, Jean Marie

AU - Welch, Alan J.

PY - 1981

Y1 - 1981

N2 - The arachno-carbaborane 1,3-C2B7H13 reacts with [Co(PEt3)4] and with [Rh(η-C3H5)(PEt3)2] to afford, respectively, [2-H-2,2-(Et3P)2-1,6,2-C2CoB7H9] and [2-H-2,2-(Et3P)2-1,6,2-C 2RhB7H9]; both structures have been established by X-ray diffraction studies, but, whilst they crystallise in nearly identical unit cells and the same space group, these species are not isostructural.

AB - The arachno-carbaborane 1,3-C2B7H13 reacts with [Co(PEt3)4] and with [Rh(η-C3H5)(PEt3)2] to afford, respectively, [2-H-2,2-(Et3P)2-1,6,2-C2CoB7H9] and [2-H-2,2-(Et3P)2-1,6,2-C 2RhB7H9]; both structures have been established by X-ray diffraction studies, but, whilst they crystallise in nearly identical unit cells and the same space group, these species are not isostructural.

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U2 - 10.1039/C39810000653

DO - 10.1039/C39810000653

M3 - Article

SN - 0022-4936

SP - 653

EP - 655

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 13

ER -

Barker GK, Garcia MP, Green M, Stone FGA, Bassett JM, Welch AJ. closo-Carbametallaboranes with Metal-Hydrogen Bonds from Direct Insertion into arachno-Carbaboranes: The Molecular Structures of [2-H-2,2-(Et₃P)₂-1,6,2-C₂CoB₇H₉] and[2-H-2,2-(Et₃P)₂-1,6,2-C₂RhB₇H₉] and a Most Unusual Crystallographic Coincidence. Journal of the Chemical Society, Chemical Communications. 1981;(13):653-655. doi: 10.1039/C39810000653