Hybrid lanthanide double-deckers based on calixarene and polyoxometalate units

Yushu Jiao, Sergio Sanz, Natalya V. Izarova, Jan van Leusen, Sidra Sarwar, Scott J. Dalgarno, Euan K. Brechin, Paul Kögerler

Research output: Contribution to journalArticlepeer-review

Abstract

Complementarity of calixarene (H 2L) and polyoxometalate ligands results in the first organic-inorganic [M IIIL{Mo 5O 13(OMe) 4(NO)}] 2− (M = Y, Gd and Dy) hybrid, directing the formation of a distorted square-antiprismatic MO 8 ligand field and resulting in slow relaxation of the magnetisation for the Dy derivative.

Original languageEnglish
Pages (from-to)5409-5413
Number of pages5
JournalDalton Transactions
Volume51
Issue number14
Early online date15 Mar 2022
DOIs
Publication statusPublished - 15 Mar 2022

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