High temperature neutron diffraction studies of phase transformations in NiCr2S4

Paz Vaqueiro, Steve Hull, Bente Lebech, Anthony V. Powell

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

High temperature structural transformations in NiCr2S4 have been investigated by neutron powder diffraction in situ. At 835(5) °C, NiCr2S4 undergoes an order-disorder transition from the monoclinic Cr3S4 structure to a hexagonal cation-deficient NiAs structure. Above the transition temperature, cation vacancies, which at room temperature are ordered in every second cation layer, become statistically distributed between all cation layers. Prior to this structural transition, intralayer disordering of vacancies occurs within the half-occupied layer. This is not sufficiently complete to cause the change to trigonal symmetry which has been reported for binary sulfides.

Original languageEnglish
Pages (from-to)2859-2863
Number of pages5
JournalJournal of Materials Chemistry
Volume9
Issue number11
DOIs
Publication statusPublished - 1999

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