Haloaryl carboranes. I. 1,4-bis[2-phenyl-1,2-dicarba-closo-dodecaboran(12)-1-yl]-2,3,5,6- tetrafluorobenzene

Rhodri Ll Thomas; Alan J. Welch

Haloaryl carboranes. I. 1,4-bis[2-phenyl-1,2-dicarba-closo-dodecaboran(12)-1-yl]-2,3,5,6- tetrafluorobenzene

Rhodri Ll Thomas
, Alan J. Welch

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

The title molecule, C₂₂H₃₀B₂₀F₄, has a crystallographically imposed inversion centre. The twist angle (?) of the phenyl ring is 15.6 (3)°, and that of the haloaryl ring is 3.7 (3)°. These low values are presumably a consequence of the mutual steric crowding of the rings. The C_cage - C_cage distance is 1.730 (3) Å, in good agreement with that found in similar molecules.

Original language	English
Pages (from-to)	1689-1691
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	7
Publication status	Published - 15 Jul 1996

Cite this

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title = "Haloaryl carboranes. I. 1,4-bis[2-phenyl-1,2-dicarba-closo-dodecaboran(12)-1-yl]-2,3,5,6- tetrafluorobenzene",

abstract = "The title molecule, C22H30B20F4, has a crystallographically imposed inversion centre. The twist angle (?) of the phenyl ring is 15.6 (3)°, and that of the haloaryl ring is 3.7 (3)°. These low values are presumably a consequence of the mutual steric crowding of the rings. The Ccage - Ccage distance is 1.730 (3) {\AA}, in good agreement with that found in similar molecules.",

author = "Thomas, \{Rhodri Ll\} and Welch, \{Alan J.\}",

year = "1996",

month = jul,

day = "15",

language = "English",

volume = "52",

pages = "1689--1691",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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T1 - Haloaryl carboranes. I. 1,4-bis[2-phenyl-1,2-dicarba-closo-dodecaboran(12)-1-yl]-2,3,5,6- tetrafluorobenzene

AU - Thomas, Rhodri Ll

AU - Welch, Alan J.

PY - 1996/7/15

Y1 - 1996/7/15

N2 - The title molecule, C22H30B20F4, has a crystallographically imposed inversion centre. The twist angle (?) of the phenyl ring is 15.6 (3)°, and that of the haloaryl ring is 3.7 (3)°. These low values are presumably a consequence of the mutual steric crowding of the rings. The Ccage - Ccage distance is 1.730 (3) Å, in good agreement with that found in similar molecules.

AB - The title molecule, C22H30B20F4, has a crystallographically imposed inversion centre. The twist angle (?) of the phenyl ring is 15.6 (3)°, and that of the haloaryl ring is 3.7 (3)°. These low values are presumably a consequence of the mutual steric crowding of the rings. The Ccage - Ccage distance is 1.730 (3) Å, in good agreement with that found in similar molecules.

UR - https://www.scopus.com/pages/publications/0030192205

M3 - Article

SN - 0108-2701

VL - 52

SP - 1689

EP - 1691

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 7

ER -

Haloaryl carboranes. I. 1,4-bis[2-phenyl-1,2-dicarba-closo-dodecaboran(12)-1-yl]-2,3,5,6- tetrafluorobenzene

Abstract

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