Gold(I)-catalysed iodoalkoxylation of allenes

Amelie Heuer-Jungemann; Ross G. McLaren; Maximillian S. Hadfield; Ai L. Lee

doi:10.1016/j.tet.2011.01.021

Gold(I)-catalysed iodoalkoxylation of allenes

Amelie Heuer-Jungemann, Ross G. McLaren, Maximillian S. Hadfield, Ai L. Lee

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Gold(I)-catalysed intermolecular iodoalkoxylation of allenes occurs in a regioselective and stereoselective manner to produce versatile iodo-tert-allyllic ether products. The products can be further elaborated through cross-couplings to yield highly substituted tert-allylic ethers. © 2011 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	1609-1616
Number of pages	8
Journal	Tetrahedron
Volume	67
Issue number	9
DOIs	https://doi.org/10.1016/j.tet.2011.01.021
Publication status	Published - 4 Mar 2011

Keywords

Allenes
Ethers
Gold catalysis
Iodoalkoxylation

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10.1016/j.tet.2011.01.021

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title = "Gold(I)-catalysed iodoalkoxylation of allenes",

abstract = "Gold(I)-catalysed intermolecular iodoalkoxylation of allenes occurs in a regioselective and stereoselective manner to produce versatile iodo-tert-allyllic ether products. The products can be further elaborated through cross-couplings to yield highly substituted tert-allylic ethers. {\textcopyright} 2011 Elsevier Ltd. All rights reserved.",

keywords = "Allenes, Ethers, Gold catalysis, Iodoalkoxylation",

author = "Amelie Heuer-Jungemann and McLaren, {Ross G.} and Hadfield, {Maximillian S.} and Lee, {Ai L.}",

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AU - Heuer-Jungemann, Amelie

AU - McLaren, Ross G.

AU - Hadfield, Maximillian S.

AU - Lee, Ai L.

PY - 2011/3/4

Y1 - 2011/3/4

N2 - Gold(I)-catalysed intermolecular iodoalkoxylation of allenes occurs in a regioselective and stereoselective manner to produce versatile iodo-tert-allyllic ether products. The products can be further elaborated through cross-couplings to yield highly substituted tert-allylic ethers. © 2011 Elsevier Ltd. All rights reserved.

AB - Gold(I)-catalysed intermolecular iodoalkoxylation of allenes occurs in a regioselective and stereoselective manner to produce versatile iodo-tert-allyllic ether products. The products can be further elaborated through cross-couplings to yield highly substituted tert-allylic ethers. © 2011 Elsevier Ltd. All rights reserved.

KW - Allenes

KW - Ethers

KW - Gold catalysis

KW - Iodoalkoxylation

UR - http://www.scopus.com/inward/record.url?scp=79851511496&partnerID=8YFLogxK

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DO - 10.1016/j.tet.2011.01.021

M3 - Article

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JO - Tetrahedron

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IS - 9

ER -

Gold(I)-catalysed iodoalkoxylation of allenes

Abstract

Keywords

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