TY - JOUR
T1 - Gas phase reactions of sodium. IV. Rates of reaction of methylchlorogermanes and -stannanes
AU - Boak, D. S.
AU - Friswell, N. J.
AU - Gowenlock, B. G.
PY - 1971/3/16
Y1 - 1971/3/16
N2 - The rates of reaction with sodium atoms of the compounds Me3MCl and Me2MCl2 (M = Ge, Sn) have been measured. The gradations in velocity constants along the Group IV series Me3MCl (M = C, Si, Ge, Sn) are discussed in terms of bond dissociation energies. It is concluded that the reaction rate of trimethylchlorostannane is high and reasons for this behaviour are discussed. © 1971 Elsevier Sequoia S.A., Lausanne.
AB - The rates of reaction with sodium atoms of the compounds Me3MCl and Me2MCl2 (M = Ge, Sn) have been measured. The gradations in velocity constants along the Group IV series Me3MCl (M = C, Si, Ge, Sn) are discussed in terms of bond dissociation energies. It is concluded that the reaction rate of trimethylchlorostannane is high and reasons for this behaviour are discussed. © 1971 Elsevier Sequoia S.A., Lausanne.
UR - http://www.scopus.com/inward/record.url?scp=49649148050&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)82162-2
DO - 10.1016/S0022-328X(00)82162-2
M3 - Article
VL - 27
SP - 333
EP - 336
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 3
ER -