Gas phase reactions of sodium. IV. Rates of reaction of methylchlorogermanes and -stannanes

D. S. Boak; N. J. Friswell; B. G. Gowenlock

doi:10.1016/S0022-328X(00)82162-2

Gas phase reactions of sodium. IV. Rates of reaction of methylchlorogermanes and -stannanes

D. S. Boak, N. J. Friswell, B. G. Gowenlock

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article

Abstract

The rates of reaction with sodium atoms of the compounds Me₃MCl and Me₂MCl₂ (M = Ge, Sn) have been measured. The gradations in velocity constants along the Group IV series Me₃MCl (M = C, Si, Ge, Sn) are discussed in terms of bond dissociation energies. It is concluded that the reaction rate of trimethylchlorostannane is high and reasons for this behaviour are discussed. © 1971 Elsevier Sequoia S.A., Lausanne.

Original language	English
Pages (from-to)	333-336
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	27
Issue number	3
DOIs	https://doi.org/10.1016/S0022-328X(00)82162-2
Publication status	Published - 16 Mar 1971

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Boak, D. S., Friswell, N. J., & Gowenlock, B. G. (1971). Gas phase reactions of sodium. IV. Rates of reaction of methylchlorogermanes and -stannanes. Journal of Organometallic Chemistry, 27(3), 333-336. https://doi.org/10.1016/S0022-328X(00)82162-2

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abstract = "The rates of reaction with sodium atoms of the compounds Me3MCl and Me2MCl2 (M = Ge, Sn) have been measured. The gradations in velocity constants along the Group IV series Me3MCl (M = C, Si, Ge, Sn) are discussed in terms of bond dissociation energies. It is concluded that the reaction rate of trimethylchlorostannane is high and reasons for this behaviour are discussed. {\textcopyright} 1971 Elsevier Sequoia S.A., Lausanne.",

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AB - The rates of reaction with sodium atoms of the compounds Me3MCl and Me2MCl2 (M = Ge, Sn) have been measured. The gradations in velocity constants along the Group IV series Me3MCl (M = C, Si, Ge, Sn) are discussed in terms of bond dissociation energies. It is concluded that the reaction rate of trimethylchlorostannane is high and reasons for this behaviour are discussed. © 1971 Elsevier Sequoia S.A., Lausanne.

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