Functionalized polydiacetylenes with polar, hydrogen bonding and metal-containing groups

I. H. Jenkins; C. Murray; W. E. Lindsell; P. N. Preston; T. A J Woodman

Functionalized polydiacetylenes with polar, hydrogen bonding and metal-containing groups

I. H. Jenkins, C. Murray, W. E. Lindsell, P. N. Preston, T. A J Woodman

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

Polydiacetylenes [C(R)C=CC(R)]_n (PDA's) are of interest for their third-order nonlinear optical behaviour and for their thermo- or solvato-chromic properties. We have previously described synthetic and physical studies on soluble PDA's, including polymers with coordinated metal units. We now report the preparation and characterization of new PDA's incorporating polar, hydrogen bonding and metal-containing groups. In this contribution, the following polydiacetylenes will be described: (1) ionic ammonium and phosphonium derivatives and ammonium sulfonate inner salts. (2) adenine- and thymine-substituted polymers with the potential for generation of intermolecular hydrogen bonded species in solution. (3) phosphine- and 2,2'-bipyridyl-containing derivatives and metal complexes derived therefrom. Comparative nonlinear optical studies on selected new materials will be described.

Original language	English
Pages (from-to)	324-
Journal	Polymeric Materials Science and Engineering
Volume	76
Publication status	Published - 1997
Event	Proceedings of the 1997 Spring ACS Meeting - San Francisco, CA, USA Duration: 13 Apr 1997 → 17 Apr 1997

Cite this

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title = "Functionalized polydiacetylenes with polar, hydrogen bonding and metal-containing groups",

abstract = "Polydiacetylenes [C(R)C=CC(R)]n (PDA's) are of interest for their third-order nonlinear optical behaviour and for their thermo- or solvato-chromic properties. We have previously described synthetic and physical studies on soluble PDA's, including polymers with coordinated metal units. We now report the preparation and characterization of new PDA's incorporating polar, hydrogen bonding and metal-containing groups. In this contribution, the following polydiacetylenes will be described: (1) ionic ammonium and phosphonium derivatives and ammonium sulfonate inner salts. (2) adenine- and thymine-substituted polymers with the potential for generation of intermolecular hydrogen bonded species in solution. (3) phosphine- and 2,2'-bipyridyl-containing derivatives and metal complexes derived therefrom. Comparative nonlinear optical studies on selected new materials will be described.",

author = "Jenkins, {I. H.} and C. Murray and Lindsell, {W. E.} and Preston, {P. N.} and Woodman, {T. A J}",

year = "1997",

language = "English",

volume = "76",

pages = "324--",

journal = "Polymeric Materials Science and Engineering",

publisher = "American Chemical Society",

note = "Proceedings of the 1997 Spring ACS Meeting ; Conference date: 13-04-1997 Through 17-04-1997",

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TY - JOUR

T1 - Functionalized polydiacetylenes with polar, hydrogen bonding and metal-containing groups

AU - Jenkins, I. H.

AU - Murray, C.

AU - Lindsell, W. E.

AU - Preston, P. N.

AU - Woodman, T. A J

PY - 1997

Y1 - 1997

N2 - Polydiacetylenes [C(R)C=CC(R)]n (PDA's) are of interest for their third-order nonlinear optical behaviour and for their thermo- or solvato-chromic properties. We have previously described synthetic and physical studies on soluble PDA's, including polymers with coordinated metal units. We now report the preparation and characterization of new PDA's incorporating polar, hydrogen bonding and metal-containing groups. In this contribution, the following polydiacetylenes will be described: (1) ionic ammonium and phosphonium derivatives and ammonium sulfonate inner salts. (2) adenine- and thymine-substituted polymers with the potential for generation of intermolecular hydrogen bonded species in solution. (3) phosphine- and 2,2'-bipyridyl-containing derivatives and metal complexes derived therefrom. Comparative nonlinear optical studies on selected new materials will be described.

AB - Polydiacetylenes [C(R)C=CC(R)]n (PDA's) are of interest for their third-order nonlinear optical behaviour and for their thermo- or solvato-chromic properties. We have previously described synthetic and physical studies on soluble PDA's, including polymers with coordinated metal units. We now report the preparation and characterization of new PDA's incorporating polar, hydrogen bonding and metal-containing groups. In this contribution, the following polydiacetylenes will be described: (1) ionic ammonium and phosphonium derivatives and ammonium sulfonate inner salts. (2) adenine- and thymine-substituted polymers with the potential for generation of intermolecular hydrogen bonded species in solution. (3) phosphine- and 2,2'-bipyridyl-containing derivatives and metal complexes derived therefrom. Comparative nonlinear optical studies on selected new materials will be described.

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M3 - Article

VL - 76

SP - 324-

JO - Polymeric Materials Science and Engineering

JF - Polymeric Materials Science and Engineering

T2 - Proceedings of the 1997 Spring ACS Meeting

Y2 - 13 April 1997 through 17 April 1997

ER -

Functionalized polydiacetylenes with polar, hydrogen bonding and metal-containing groups

Abstract

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