Frequency-dependent effective capacitance of supercapacitors using electrospun cobalt-carbon composite nanofibers

Mohammad A. Abdelkareem, Anis Allagui, Zafar Said, Ahmed S. Elwakil, Rawan Zannerni, Waqas Hassan Tanveer, Khaled Elsaid

Research output: Contribution to journalArticle

Abstract

Mixing carbon-based materials with pseudocapacitive material is a widely used strategy to prepare high-energy, high-power supercapacitors. However, phase separation is inevitable after extended charging/discharging which leads to the degradation of performance metrics of the device. Here, we prepare in a single step cobalt-incorporated carbon nanofibers (CNF) by electrospinning homogeneous solutions of polyacrylonitrile (PAN) with cobalt acetate at different nominal proportions (1:0 to 1:1), and investigate their stability and capacitive behavior in symmetric supercapacitors. The electrochemical analyzes demonstrated up to an order of magnitude increase in the effective capacitive with increasing the cobalt content at both close-to-dc frequencies and at around 50/60 Hz power line frequencies. The maximum capacitance is recorded for a nominal cobalt acetate-to-PAN ratio of 0.9 (e.g. 29, 27, 22 and 10 mF at 0.01. 0.1, 1 and 100 Hz respectively; both electrodes are loaded with 1 mg cm−2 of active material each). All devices showed also an outstanding capacitance retention exceeding 99% for 10000 cycles at 1 mA and 5 mA charging/discharging rates each. The improved energy storage capabilities are attributed to both the increased electrical conductivity and high pyridinic nitrogen content which was revealed from the material characterization results using XRD, FE-SEM/TEM, and XPS.

Original languageEnglish
Pages (from-to)A2403-A2408
Number of pages6
JournalJournal of The Electrochemical Society
Volume166
Issue number12
DOIs
Publication statusPublished - 5 Jul 2019

Fingerprint

Nanofibers
Cobalt
Capacitance
Carbon
Polyacrylonitriles
Composite materials
Acetates
Carbon nanofibers
Electrospinning
Phase separation
Energy storage
Nitrogen
X ray photoelectron spectroscopy
Transmission electron microscopy
Degradation
Scanning electron microscopy
Electrodes
Supercapacitor
polyacrylonitrile

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Cite this

Abdelkareem, Mohammad A. ; Allagui, Anis ; Said, Zafar ; Elwakil, Ahmed S. ; Zannerni, Rawan ; Tanveer, Waqas Hassan ; Elsaid, Khaled. / Frequency-dependent effective capacitance of supercapacitors using electrospun cobalt-carbon composite nanofibers. In: Journal of The Electrochemical Society. 2019 ; Vol. 166, No. 12. pp. A2403-A2408.
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Frequency-dependent effective capacitance of supercapacitors using electrospun cobalt-carbon composite nanofibers. / Abdelkareem, Mohammad A.; Allagui, Anis; Said, Zafar; Elwakil, Ahmed S.; Zannerni, Rawan; Tanveer, Waqas Hassan; Elsaid, Khaled.

In: Journal of The Electrochemical Society, Vol. 166, No. 12, 05.07.2019, p. A2403-A2408.

Research output: Contribution to journalArticle

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T1 - Frequency-dependent effective capacitance of supercapacitors using electrospun cobalt-carbon composite nanofibers

AU - Abdelkareem, Mohammad A.

AU - Allagui, Anis

AU - Said, Zafar

AU - Elwakil, Ahmed S.

AU - Zannerni, Rawan

AU - Tanveer, Waqas Hassan

AU - Elsaid, Khaled

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