Fourteen-vertex homo- and heterobimetallic metallacarboranes

David Ellis; M E Lopez; Ruaraidh McIntosh; Georgina M. Rosair; Alan J. Welch

doi:10.1039/b500236b

Fourteen-vertex homo- and heterobimetallic metallacarboranes

David Ellis, M E Lopez, Ruaraidh McIntosh, Georgina M. Rosair, Alan J. Welch

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Reduction of 4-(p-cymene)-4,1,12-closo-RuC₂B₁₀H ₁₂ followed by metallation with {M'} fragments (M' = {CpCo²⁺}, {(arene)Ru²⁺} or {(dppe)Ni²⁺}) affords 14-vertex bimetallic 1,14,2,10-RuM'C₂B₁₀ species having bicapped hexagonal anti-prismatic structures. © The Royal Society of Chemistry 2005.

Original language	English
Pages (from-to)	1917-1919
Number of pages	3
Journal	Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/b500236b
Publication status	Published - 14 Apr 2005

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10.1039/b500236b

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abstract = "Reduction of 4-(p-cymene)-4,1,12-closo-RuC2B10H 12 followed by metallation with {M'} fragments (M' = {CpCo2+}, {(arene)Ru2+} or {(dppe)Ni2+}) affords 14-vertex bimetallic 1,14,2,10-RuM'C2B10 species having bicapped hexagonal anti-prismatic structures. {\textcopyright} The Royal Society of Chemistry 2005.",

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AU - Ellis, David

AU - Lopez, M E

AU - McIntosh, Ruaraidh

AU - Rosair, Georgina M.

AU - Welch, Alan J.

PY - 2005/4/14

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N2 - Reduction of 4-(p-cymene)-4,1,12-closo-RuC2B10H 12 followed by metallation with {M'} fragments (M' = {CpCo2+}, {(arene)Ru2+} or {(dppe)Ni2+}) affords 14-vertex bimetallic 1,14,2,10-RuM'C2B10 species having bicapped hexagonal anti-prismatic structures. © The Royal Society of Chemistry 2005.

AB - Reduction of 4-(p-cymene)-4,1,12-closo-RuC2B10H 12 followed by metallation with {M'} fragments (M' = {CpCo2+}, {(arene)Ru2+} or {(dppe)Ni2+}) affords 14-vertex bimetallic 1,14,2,10-RuM'C2B10 species having bicapped hexagonal anti-prismatic structures. © The Royal Society of Chemistry 2005.

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JF - Chemical Communications

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ER -

Fourteen-vertex homo- and heterobimetallic metallacarboranes

Abstract

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