Formation of h6-Arene-closo-carbaferraboranes by the Reactionof a closo-Carbaborane withCyclo-octadiene(h-cyclopentadienyl)ironin the Presence of Arenes:  MolecularStructure of (h6-PhMe)-2,4-Me2-1,2,4-FeC2B9H9]

Maria P. Garcia; Michael Green; F. Gordon A. Stone; Richard G. Somerville; Alan J. Welch

doi:10.1039/C39810000871

Formation of h⁶-Arene-closo-carbaferraboranes by the Reactionof a closo-Carbaborane withCyclo-octadiene(h-cyclopentadienyl)ironin the Presence of Arenes: MolecularStructure of (h⁶-PhMe)-2,4-Me₂-1,2,4-FeC₂B₉H₉]

Maria P. Garcia^*, Michael Green, F. Gordon A. Stone, Richard G. Somerville, Alan J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

Reaction of 2,3-Me₂-2,3-C₂B₉H₉ with [Fe(1,5-C₈H₁₂)(η-C₅H₅)] in benzene, toluene, o-xylene, or with an excess of naphthalene in light petroleum, affords the complexes [closo-1-(η⁶-arene)-2,4-Me ₂-1,2,4-FeC₂B₉H₉], the identity of the toluene complex being established by X-ray crystallography; reaction of the η⁶-naphthalene complex with the ligands L = CO or P(OMe) ₃ affords [closo-1, 1, 1-L₃-2,4-Me₂-1,2,4- FeC₂B₉H₉].

Original language	English
Pages (from-to)	871-872
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39810000871
Publication status	Published - 1981

ASJC Scopus subject areas

Molecular Medicine

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Garcia, M. P., Green, M., Stone, F. G. A., Somerville, R. G., & Welch, A. J. (1981). Formation of h⁶-Arene-closo-carbaferraboranes by the Reactionof a closo-Carbaborane withCyclo-octadiene(h-cyclopentadienyl)ironin the Presence of Arenes: MolecularStructure of (h⁶-PhMe)-2,4-Me₂-1,2,4-FeC₂B₉H₉]. Journal of the Chemical Society, Chemical Communications, (16), 871-872. https://doi.org/10.1039/C39810000871

@article{24d4808f02cf415d889fe9250d4c22b6,

title = "Formation of h6-Arene-closo-carbaferraboranes by the Reactionof a closo-Carbaborane withCyclo-octadiene(h-cyclopentadienyl)ironin the Presence of Arenes: MolecularStructure of (h6-PhMe)-2,4-Me2-1,2,4-FeC2B9H9]",

abstract = "Reaction of 2,3-Me2-2,3-C2B9H9 with [Fe(1,5-C8H12)(η-C5H5)] in benzene, toluene, o-xylene, or with an excess of naphthalene in light petroleum, affords the complexes [closo-1-(η6-arene)-2,4-Me 2-1,2,4-FeC2B9H9], the identity of the toluene complex being established by X-ray crystallography; reaction of the η6-naphthalene complex with the ligands L = CO or P(OMe) 3 affords [closo-1, 1, 1-L3-2,4-Me2-1,2,4- FeC2B9H9].",

author = "Garcia, {Maria P.} and Michael Green and Stone, {F. Gordon A.} and Somerville, {Richard G.} and Welch, {Alan J.}",

year = "1981",

doi = "10.1039/C39810000871",

language = "English",

pages = "871--872",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "16",

}

Garcia, MP, Green, M, Stone, FGA, Somerville, RG & Welch, AJ 1981, 'Formation of h⁶-Arene-closo-carbaferraboranes by the Reactionof a closo-Carbaborane withCyclo-octadiene(h-cyclopentadienyl)ironin the Presence of Arenes: MolecularStructure of (h⁶-PhMe)-2,4-Me₂-1,2,4-FeC₂B₉H₉]', Journal of the Chemical Society, Chemical Communications, no. 16, pp. 871-872. https://doi.org/10.1039/C39810000871

Formation of h⁶-Arene-closo-carbaferraboranes by the Reactionof a closo-Carbaborane withCyclo-octadiene(h-cyclopentadienyl)ironin the Presence of Arenes: MolecularStructure of (h⁶-PhMe)-2,4-Me₂-1,2,4-FeC₂B₉H₉]. / Garcia, Maria P.; Green, Michael; Stone, F. Gordon A. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 16, 1981, p. 871-872.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Formation of h6-Arene-closo-carbaferraboranes by the Reactionof a closo-Carbaborane withCyclo-octadiene(h-cyclopentadienyl)ironin the Presence of Arenes: MolecularStructure of (h6-PhMe)-2,4-Me2-1,2,4-FeC2B9H9]

AU - Garcia, Maria P.

AU - Green, Michael

AU - Stone, F. Gordon A.

AU - Somerville, Richard G.

AU - Welch, Alan J.

PY - 1981

Y1 - 1981

N2 - Reaction of 2,3-Me2-2,3-C2B9H9 with [Fe(1,5-C8H12)(η-C5H5)] in benzene, toluene, o-xylene, or with an excess of naphthalene in light petroleum, affords the complexes [closo-1-(η6-arene)-2,4-Me 2-1,2,4-FeC2B9H9], the identity of the toluene complex being established by X-ray crystallography; reaction of the η6-naphthalene complex with the ligands L = CO or P(OMe) 3 affords [closo-1, 1, 1-L3-2,4-Me2-1,2,4- FeC2B9H9].

AB - Reaction of 2,3-Me2-2,3-C2B9H9 with [Fe(1,5-C8H12)(η-C5H5)] in benzene, toluene, o-xylene, or with an excess of naphthalene in light petroleum, affords the complexes [closo-1-(η6-arene)-2,4-Me 2-1,2,4-FeC2B9H9], the identity of the toluene complex being established by X-ray crystallography; reaction of the η6-naphthalene complex with the ligands L = CO or P(OMe) 3 affords [closo-1, 1, 1-L3-2,4-Me2-1,2,4- FeC2B9H9].

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U2 - 10.1039/C39810000871

DO - 10.1039/C39810000871

M3 - Article

SN - 0022-4936

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 16

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Garcia MP, Green M, Stone FGA, Somerville RG, Welch AJ. Formation of h⁶-Arene-closo-carbaferraboranes by the Reactionof a closo-Carbaborane withCyclo-octadiene(h-cyclopentadienyl)ironin the Presence of Arenes: MolecularStructure of (h⁶-PhMe)-2,4-Me₂-1,2,4-FeC₂B₉H₉]. Journal of the Chemical Society, Chemical Communications. 1981;(16):871-872. doi: 10.1039/C39810000871