TY - JOUR
T1 - Formation of closo- and nido-metallocarboranes from closo-C2B9 and -C2B7 carborbranes; molecular structures of closo-1,1-(Me2PhP)2-2,4-Me2-1,2,4-PtC2B9H9 and nido-10,10-(Et3P)2-2,8-Me2-10,2,8-PtC2B7H7
AU - Green, Michael
AU - Spencer, John L.
AU - Stone, F. Gordon A.
AU - Welch, Alan J.
PY - 1974
Y1 - 1974
N2 - Reaction of closo-1,6-Me2-1,6-C2B7H 7 with [Pt(Et3P)3] affords nido-10,10-(Et 3P)2-2,8-Me2-10,2,8-PtC2B 7H7, a stereochemically non-rigid molecule; the structural identity of closo-1,1-(Me2PhP)2-2,4-Me 2-1,2,4-PtC2B9H9 and the nido-metallocarborane are established by X-ray crystallography.
AB - Reaction of closo-1,6-Me2-1,6-C2B7H 7 with [Pt(Et3P)3] affords nido-10,10-(Et 3P)2-2,8-Me2-10,2,8-PtC2B 7H7, a stereochemically non-rigid molecule; the structural identity of closo-1,1-(Me2PhP)2-2,4-Me 2-1,2,4-PtC2B9H9 and the nido-metallocarborane are established by X-ray crystallography.
UR - http://www.scopus.com/inward/record.url?scp=37049123738&partnerID=8YFLogxK
U2 - 10.1039/C39740000571
DO - 10.1039/C39740000571
M3 - Article
SN - 0022-4936
SP - 571
EP - 572
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 14
ER -