Formation of closo- and nido-metallocarboranes from closo-C2B9 and -C2B7 carborbranes; molecular structures of closo-1,1-(Me2PhP)2-2,4-Me2-1,2,4-PtC2B9H9 and nido-10,10-(Et3P)2-2,8-Me2-10,2,8-PtC2B7H7

Michael Green; John L. Spencer; F. Gordon A. Stone; Alan J. Welch

doi:10.1039/C39740000571

Formation of closo- and nido-metallocarboranes from closo-C₂B₉ and -C₂B₇ carborbranes; molecular structures of closo-1,1-(Me₂PhP)₂-2,4-Me₂-1,2,4-PtC₂B₉H₉ and nido-10,10-(Et₃P)₂-2,8-Me₂-10,2,8-PtC₂B₇H₇

Michael Green, John L. Spencer, F. Gordon A. Stone^*, Alan J. Welch

^*Corresponding author for this work

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Abstract

Reaction of closo-1,6-Me₂-1,6-C₂B₇H ₇ with [Pt(Et₃P)₃] affords nido-10,10-(Et ₃P)₂-2,8-Me₂-10,2,8-PtC₂B ₇H₇, a stereochemically non-rigid molecule; the structural identity of closo-1,1-(Me₂PhP)₂-2,4-Me ₂-1,2,4-PtC₂B₉H₉ and the nido-metallocarborane are established by X-ray crystallography.

Original language	English
Pages (from-to)	571-572
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	14
DOIs	https://doi.org/10.1039/C39740000571
Publication status	Published - 1974

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Molecular Medicine

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Green, M., Spencer, J. L., Stone, F. G. A., & Welch, A. J. (1974). Formation of closo- and nido-metallocarboranes from closo-C₂B₉ and -C₂B₇ carborbranes; molecular structures of closo-1,1-(Me₂PhP)₂-2,4-Me₂-1,2,4-PtC₂B₉H₉ and nido-10,10-(Et₃P)₂-2,8-Me₂-10,2,8-PtC₂B₇H₇. Journal of the Chemical Society, Chemical Communications, (14), 571-572. https://doi.org/10.1039/C39740000571

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title = "Formation of closo- and nido-metallocarboranes from closo-C2B9 and -C2B7 carborbranes; molecular structures of closo-1,1-(Me2PhP)2-2,4-Me2-1,2,4-PtC2B9H9 and nido-10,10-(Et3P)2-2,8-Me2-10,2,8-PtC2B7H7",

abstract = "Reaction of closo-1,6-Me2-1,6-C2B7H 7 with [Pt(Et3P)3] affords nido-10,10-(Et 3P)2-2,8-Me2-10,2,8-PtC2B 7H7, a stereochemically non-rigid molecule; the structural identity of closo-1,1-(Me2PhP)2-2,4-Me 2-1,2,4-PtC2B9H9 and the nido-metallocarborane are established by X-ray crystallography.",

author = "Michael Green and Spencer, {John L.} and Stone, {F. Gordon A.} and Welch, {Alan J.}",

year = "1974",

doi = "10.1039/C39740000571",

language = "English",

pages = "571--572",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "14",

}

Green, M, Spencer, JL, Stone, FGA & Welch, AJ 1974, 'Formation of closo- and nido-metallocarboranes from closo-C₂B₉ and -C₂B₇ carborbranes; molecular structures of closo-1,1-(Me₂PhP)₂-2,4-Me₂-1,2,4-PtC₂B₉H₉ and nido-10,10-(Et₃P)₂-2,8-Me₂-10,2,8-PtC₂B₇H₇', Journal of the Chemical Society, Chemical Communications, no. 14, pp. 571-572. https://doi.org/10.1039/C39740000571

Formation of closo- and nido-metallocarboranes from closo-C₂B₉ and -C₂B₇ carborbranes; molecular structures of closo-1,1-(Me₂PhP)₂-2,4-Me₂-1,2,4-PtC₂B₉H₉ and nido-10,10-(Et₃P)₂-2,8-Me₂-10,2,8-PtC₂B₇H₇. / Green, Michael; Spencer, John L.; Stone, F. Gordon A. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 14, 1974, p. 571-572.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Formation of closo- and nido-metallocarboranes from closo-C2B9 and -C2B7 carborbranes; molecular structures of closo-1,1-(Me2PhP)2-2,4-Me2-1,2,4-PtC2B9H9 and nido-10,10-(Et3P)2-2,8-Me2-10,2,8-PtC2B7H7

AU - Green, Michael

AU - Spencer, John L.

AU - Stone, F. Gordon A.

AU - Welch, Alan J.

PY - 1974

Y1 - 1974

N2 - Reaction of closo-1,6-Me2-1,6-C2B7H 7 with [Pt(Et3P)3] affords nido-10,10-(Et 3P)2-2,8-Me2-10,2,8-PtC2B 7H7, a stereochemically non-rigid molecule; the structural identity of closo-1,1-(Me2PhP)2-2,4-Me 2-1,2,4-PtC2B9H9 and the nido-metallocarborane are established by X-ray crystallography.

AB - Reaction of closo-1,6-Me2-1,6-C2B7H 7 with [Pt(Et3P)3] affords nido-10,10-(Et 3P)2-2,8-Me2-10,2,8-PtC2B 7H7, a stereochemically non-rigid molecule; the structural identity of closo-1,1-(Me2PhP)2-2,4-Me 2-1,2,4-PtC2B9H9 and the nido-metallocarborane are established by X-ray crystallography.

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DO - 10.1039/C39740000571

M3 - Article

SN - 0022-4936

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EP - 572

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

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ER -

Formation of closo- and nido-metallocarboranes from closo-C₂B₉ and -C₂B₇ carborbranes; molecular structures of closo-1,1-(Me₂PhP)₂-2,4-Me₂-1,2,4-PtC₂B₉H₉ and nido-10,10-(Et₃P)₂-2,8-Me₂-10,2,8-PtC₂B₇H₇

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