Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4]

Alasdair I. McKay; Tobias Krämer; Nicholas H. Rees; Amber L.  Thompson; Kirsten E. Christensen; Stuart Alan Macgregor; Andrew S Weller

doi:10.1021/acs.organomet.6b00645

Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp₂PCH₂CH₂PCyp₂)(η²:η²-C₇H₁₂)][BAr^F₄]

Alasdair I. McKay
, Tobias Krämer
, Nicholas H. Rees
, Amber L. Thompson
, Kirsten E. Christensen
, Stuart Alan Macgregor
, Andrew S Weller

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

66 Downloads (Pure)

Abstract

Addition of H₂ to the precursor [Rh(Cyp₂PCH₂CH₂PCyp₂)(η²:η²-C₇H₈)][BAr^F₄] gives the σ-alkane complex [Rh(Cyp₂PCH₂CH₂PCyp₂)(η²:η²-C₇H₁₂)][BAr^F₄] by a single-crystal to single-crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L₂)}⁺ fragment is revealed.

Original language	English
Pages (from-to)	22-25
Number of pages	4
Journal	Organometallics
Volume	36
Issue number	1
Early online date	23 Sept 2016
DOIs	https://doi.org/10.1021/acs.organomet.6b00645
Publication status	Published - 9 Jan 2017

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title = "Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4]",

abstract = "Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H8)][BArF4] gives the σ-alkane complex [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4] by a single-crystal to single-crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the \{Rh(L2)\}+ fragment is revealed.",

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AU - McKay, Alasdair I.

AU - Krämer, Tobias

AU - Rees, Nicholas H.

AU - Thompson, Amber L.

AU - Christensen, Kirsten E.

AU - Macgregor, Stuart Alan

AU - Weller, Andrew S

PY - 2017/1/9

Y1 - 2017/1/9

N2 - Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H8)][BArF4] gives the σ-alkane complex [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4] by a single-crystal to single-crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.

AB - Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H8)][BArF4] gives the σ-alkane complex [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4] by a single-crystal to single-crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.

U2 - 10.1021/acs.organomet.6b00645

DO - 10.1021/acs.organomet.6b00645

M3 - Article

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VL - 36

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IS - 1

ER -

Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4]

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Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp₂PCH₂CH₂PCyp₂)(η²:η²-C₇H₁₂)][BAr^F₄]