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Formation of η3-bonded lactone complexes and eight-membered ring metallacycles with ketene groups by the insertion of acetylenes into carbon–molybdenum and –tungsten σ bonds; molecular and crystal structures of carbonyl(η-cyclopentadienyl)(3–5-η-2,3-dihydro-3,4,5-trimethyl-2-oxo-3-furyl)(t-butyl isocyanide)molybdenum and carbonyl-(η-cyclopentadienyl)(3–4:5–6-η-2,3,4,5-tetramethyl-6-oxo-1-trifluoromethylhexa-1,3,5-trienyloxo)molybdenum

  • Michael Green
  • , Jeffrey Z. Nyathi
  • , Caron Scott
  • , F. Gordon A. Stone*
  • , Alan J. Welch
  • , Peter Woodward
  • *Corresponding author for this work

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Chemistry