Ferrocene incorporating host-guest dyads with electrochemically controlled three-pole hydrogen bonding properties

Graeme Cooke; Hugues A. De Cremiers; F. M A Duclairoir; Julie Leonardi; Georgina Rosair; Vincent M. Rotello

doi:10.1016/S0040-4020(03)00423-X

Ferrocene incorporating host-guest dyads with electrochemically controlled three-pole hydrogen bonding properties

Graeme Cooke, Hugues A. De Cremiers, F. M A Duclairoir, Julie Leonardi, Georgina Rosair, Vincent M. Rotello

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

We describe the electrochemically controlled hydrogen bonding interactions between the isobutyl flavin/2,6-diferrocenylamidopyridine (2.5) and 9,10-phenanthrenequinone/1-ferrocenyl-3-hexylurea (4.6) dyads. Cyclic and square wave voltammetry studies have shown that the binding efficiencies between these moieties can be electrochemically actuated in non-polar (CH₂Cl₂ for 2.5) or polar (DMF for 4.6) organic solvents between three distinct states. © 2003 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	3341-3347
Number of pages	7
Journal	Tetrahedron
Volume	59
Issue number	18
DOIs	https://doi.org/10.1016/S0040-4020(03)00423-X
Publication status	Published - 28 Apr 2003

Keywords

Electrochemistry
Ferrocene
Hydrogen bonding
Recognition

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10.1016/S0040-4020(03)00423-X

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title = "Ferrocene incorporating host-guest dyads with electrochemically controlled three-pole hydrogen bonding properties",

abstract = "We describe the electrochemically controlled hydrogen bonding interactions between the isobutyl flavin/2,6-diferrocenylamidopyridine (2.5) and 9,10-phenanthrenequinone/1-ferrocenyl-3-hexylurea (4.6) dyads. Cyclic and square wave voltammetry studies have shown that the binding efficiencies between these moieties can be electrochemically actuated in non-polar (CH2Cl2 for 2.5) or polar (DMF for 4.6) organic solvents between three distinct states. {\textcopyright} 2003 Elsevier Science Ltd. All rights reserved.",

keywords = "Electrochemistry, Ferrocene, Hydrogen bonding, Recognition",

author = "Graeme Cooke and \{De Cremiers\}, \{Hugues A.\} and Duclairoir, \{F. M A\} and Julie Leonardi and Georgina Rosair and Rotello, \{Vincent M.\}",

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doi = "10.1016/S0040-4020(03)00423-X",

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T1 - Ferrocene incorporating host-guest dyads with electrochemically controlled three-pole hydrogen bonding properties

AU - Cooke, Graeme

AU - De Cremiers, Hugues A.

AU - Duclairoir, F. M A

AU - Leonardi, Julie

AU - Rosair, Georgina

AU - Rotello, Vincent M.

PY - 2003/4/28

Y1 - 2003/4/28

N2 - We describe the electrochemically controlled hydrogen bonding interactions between the isobutyl flavin/2,6-diferrocenylamidopyridine (2.5) and 9,10-phenanthrenequinone/1-ferrocenyl-3-hexylurea (4.6) dyads. Cyclic and square wave voltammetry studies have shown that the binding efficiencies between these moieties can be electrochemically actuated in non-polar (CH2Cl2 for 2.5) or polar (DMF for 4.6) organic solvents between three distinct states. © 2003 Elsevier Science Ltd. All rights reserved.

AB - We describe the electrochemically controlled hydrogen bonding interactions between the isobutyl flavin/2,6-diferrocenylamidopyridine (2.5) and 9,10-phenanthrenequinone/1-ferrocenyl-3-hexylurea (4.6) dyads. Cyclic and square wave voltammetry studies have shown that the binding efficiencies between these moieties can be electrochemically actuated in non-polar (CH2Cl2 for 2.5) or polar (DMF for 4.6) organic solvents between three distinct states. © 2003 Elsevier Science Ltd. All rights reserved.

KW - Electrochemistry

KW - Ferrocene

KW - Hydrogen bonding

KW - Recognition

UR - https://www.scopus.com/pages/publications/0037471513

U2 - 10.1016/S0040-4020(03)00423-X

DO - 10.1016/S0040-4020(03)00423-X

M3 - Article

SN - 1464-5416

VL - 59

SP - 3341

EP - 3347

JO - Tetrahedron

JF - Tetrahedron

IS - 18

ER -

Ferrocene incorporating host-guest dyads with electrochemically controlled three-pole hydrogen bonding properties

Abstract

Keywords

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