Ferrocene incorporating host-guest dyads with electrochemically controlled three-pole hydrogen bonding properties

Graeme Cooke, Hugues A. De Cremiers, F. M A Duclairoir, Julie Leonardi, Georgina Rosair, Vincent M. Rotello

Research output: Contribution to journalArticle

Abstract

We describe the electrochemically controlled hydrogen bonding interactions between the isobutyl flavin/2,6-diferrocenylamidopyridine (2.5) and 9,10-phenanthrenequinone/1-ferrocenyl-3-hexylurea (4.6) dyads. Cyclic and square wave voltammetry studies have shown that the binding efficiencies between these moieties can be electrochemically actuated in non-polar (CH2Cl2 for 2.5) or polar (DMF for 4.6) organic solvents between three distinct states. © 2003 Elsevier Science Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)3341-3347
Number of pages7
JournalTetrahedron
Volume59
Issue number18
DOIs
Publication statusPublished - 28 Apr 2003

Fingerprint

Voltammetry
Organic solvents
Poles
Hydrogen bonds
4,6-dinitro-o-cresol
ferrocene
9,10-phenanthrenequinone

Keywords

  • Electrochemistry
  • Ferrocene
  • Hydrogen bonding
  • Recognition

Cite this

Cooke, G., De Cremiers, H. A., Duclairoir, F. M. A., Leonardi, J., Rosair, G., & Rotello, V. M. (2003). Ferrocene incorporating host-guest dyads with electrochemically controlled three-pole hydrogen bonding properties. Tetrahedron, 59(18), 3341-3347. https://doi.org/10.1016/S0040-4020(03)00423-X
Cooke, Graeme ; De Cremiers, Hugues A. ; Duclairoir, F. M A ; Leonardi, Julie ; Rosair, Georgina ; Rotello, Vincent M. / Ferrocene incorporating host-guest dyads with electrochemically controlled three-pole hydrogen bonding properties. In: Tetrahedron. 2003 ; Vol. 59, No. 18. pp. 3341-3347.
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Cooke, G, De Cremiers, HA, Duclairoir, FMA, Leonardi, J, Rosair, G & Rotello, VM 2003, 'Ferrocene incorporating host-guest dyads with electrochemically controlled three-pole hydrogen bonding properties', Tetrahedron, vol. 59, no. 18, pp. 3341-3347. https://doi.org/10.1016/S0040-4020(03)00423-X

Ferrocene incorporating host-guest dyads with electrochemically controlled three-pole hydrogen bonding properties. / Cooke, Graeme; De Cremiers, Hugues A.; Duclairoir, F. M A; Leonardi, Julie; Rosair, Georgina; Rotello, Vincent M.

In: Tetrahedron, Vol. 59, No. 18, 28.04.2003, p. 3341-3347.

Research output: Contribution to journalArticle

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AU - Cooke, Graeme

AU - De Cremiers, Hugues A.

AU - Duclairoir, F. M A

AU - Leonardi, Julie

AU - Rosair, Georgina

AU - Rotello, Vincent M.

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AB - We describe the electrochemically controlled hydrogen bonding interactions between the isobutyl flavin/2,6-diferrocenylamidopyridine (2.5) and 9,10-phenanthrenequinone/1-ferrocenyl-3-hexylurea (4.6) dyads. Cyclic and square wave voltammetry studies have shown that the binding efficiencies between these moieties can be electrochemically actuated in non-polar (CH2Cl2 for 2.5) or polar (DMF for 4.6) organic solvents between three distinct states. © 2003 Elsevier Science Ltd. All rights reserved.

KW - Electrochemistry

KW - Ferrocene

KW - Hydrogen bonding

KW - Recognition

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