Facile synthesis of a conjugated microporous polymeric monolith via copper-free sonogashira-hagihara cross-coupling in water under aerobic conditions

Jie Liu, John Michael Tobin, Zhengtao Xu, Filipe Vilela

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

A conjugated microporous polymer was synthesized via a modified Sonogashira-Hagihara cross-coupling reaction under aerobic conditions in water and in the absence of copper. These conditions allowed for the directing of the CMP format during synthesis into a monolithic structure. Post-modification of the polymer with thiol-yne chemistry followed by AgI uptake led to a catalytically active material for a heterocyclization reaction.
Original languageEnglish
Pages (from-to)7251-7255
Number of pages5
JournalPolymer Chemistry
Volume6
Issue number41
Early online date2 Jun 2015
DOIs
Publication statusPublished - 7 Nov 2015

ASJC Scopus subject areas

  • Polymers and Plastics
  • Organic Chemistry
  • Biochemistry
  • Biomedical Engineering
  • Bioengineering

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