Abstract
A conjugated microporous polymer was synthesized via a modified Sonogashira-Hagihara cross-coupling reaction under aerobic conditions in water and in the absence of copper. These conditions allowed for the directing of the CMP format during synthesis into a monolithic structure. Post-modification of the polymer with thiol-yne chemistry followed by AgI uptake led to a catalytically active material for a heterocyclization reaction.
| Original language | English |
|---|---|
| Pages (from-to) | 7251-7255 |
| Number of pages | 5 |
| Journal | Polymer Chemistry |
| Volume | 6 |
| Issue number | 41 |
| Early online date | 2 Jun 2015 |
| DOIs | |
| Publication status | Published - 7 Nov 2015 |
ASJC Scopus subject areas
- Polymers and Plastics
- Organic Chemistry
- Biochemistry
- Biomedical Engineering
- Bioengineering
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Dive into the research topics of 'Facile synthesis of a conjugated microporous polymeric monolith via copper-free sonogashira-hagihara cross-coupling in water under aerobic conditions'. Together they form a unique fingerprint.Profiles
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Filipe Vilela
- School of Engineering & Physical Sciences - Associate Professor
- School of Engineering & Physical Sciences, Institute of Chemical Sciences - Associate Professor
Person: Academic (Research & Teaching)