Facile Isomerization and Unprecedented Decarbonation of Metallacarboranes with Fluorinated Aryl Substituents

Jas Ward; Hugo Tricas; Greig Scott; David Ellis; Georgina Margaret Rosair; Alan Jeffrey Welch

doi:10.1021/om200691z

Facile Isomerization and Unprecedented Decarbonation of Metallacarboranes with Fluorinated Aryl Substituents

Jas Ward, Hugo Tricas, Greig Scott, David Ellis, Georgina Margaret Rosair, Alan Jeffrey Welch

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Reduction and metalation of 1,2-(40-F3CC6F4)2-1,2-closo-C2B10H10
affords 4,1,12-MC2B10 compounds directly at room temperature with no evidence of intermediate 4,1,6- or 4,1,8-analogues. ForM= CpCo this species is the only isolable product. The M = Cp*Co analogue is produced together with an icosahedral
dimetallacarborane that remarkably has lost a cage C vertex

Original language	English
Pages (from-to)	2523-2525
Number of pages	3
Journal	Organometallics
Volume	31
Issue number	7
DOIs	https://doi.org/10.1021/om200691z
Publication status	Published - 2012

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title = "Facile Isomerization and Unprecedented Decarbonation of Metallacarboranes with Fluorinated Aryl Substituents",

abstract = "Reduction and metalation of 1,2-(40-F3CC6F4)2-1,2-closo-C2B10H10 affords 4,1,12-MC2B10 compounds directly at room temperature with no evidence of intermediate 4,1,6- or 4,1,8-analogues. ForM= CpCo this species is the only isolable product. The M = Cp*Co analogue is produced together with an icosahedral dimetallacarborane that remarkably has lost a cage C vertex",

author = "Jas Ward and Hugo Tricas and Greig Scott and David Ellis and Rosair, {Georgina Margaret} and Welch, {Alan Jeffrey}",

year = "2012",

doi = "10.1021/om200691z",

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journal = "Organometallics",

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T1 - Facile Isomerization and Unprecedented Decarbonation of Metallacarboranes with Fluorinated Aryl Substituents

AU - Ward, Jas

AU - Tricas, Hugo

AU - Scott, Greig

AU - Ellis, David

AU - Rosair, Georgina Margaret

AU - Welch, Alan Jeffrey

PY - 2012

Y1 - 2012

N2 - Reduction and metalation of 1,2-(40-F3CC6F4)2-1,2-closo-C2B10H10 affords 4,1,12-MC2B10 compounds directly at room temperature with no evidence of intermediate 4,1,6- or 4,1,8-analogues. ForM= CpCo this species is the only isolable product. The M = Cp*Co analogue is produced together with an icosahedral dimetallacarborane that remarkably has lost a cage C vertex

AB - Reduction and metalation of 1,2-(40-F3CC6F4)2-1,2-closo-C2B10H10 affords 4,1,12-MC2B10 compounds directly at room temperature with no evidence of intermediate 4,1,6- or 4,1,8-analogues. ForM= CpCo this species is the only isolable product. The M = Cp*Co analogue is produced together with an icosahedral dimetallacarborane that remarkably has lost a cage C vertex

U2 - 10.1021/om200691z

DO - 10.1021/om200691z

M3 - Article

SN - 1520-6041

VL - 31

SP - 2523

EP - 2525

JO - Organometallics

JF - Organometallics

IS - 7

ER -

Facile Isomerization and Unprecedented Decarbonation of Metallacarboranes with Fluorinated Aryl Substituents

Abstract

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