Facile cleavage of [RhRu3(μ-H)2(μ-CO)(CO)9(η5-C5H5)] with elimination of benzene on reaction with (Ph2PCH2)3CMe (triphos). Structural characterisation and non-rigidity of [Ru3(μ-H){μ-PPhCH2(Ph2PCH2)2CMe}(CO)8]

J. L. Le Grand; W. E. Lindsell; K. J. McCullough

Facile cleavage of [RhRu₃(μ-H)₂(μ-CO)(CO)₉(η⁵-C₅H₅)] with elimination of benzene on reaction with (Ph₂PCH₂)₃CMe (triphos). Structural characterisation and non-rigidity of [Ru₃(μ-H){μ-PPhCH₂(Ph₂PCH₂)₂CMe}(CO)₈]

J. L. Le Grand
, W. E. Lindsell
, K. J. McCullough

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of [RhRu₃(µ-H)₂(µ-CO)(CO)₉(?⁵-C₅H₅)] with (Ph₂PCH₂)₃CMe in tetrahydofuran, at or below ambient temperature, causes extensive cleavage of the cluster and intramolecular elimination of a molecule of benzene to form structurally characterised [Ru₃(µ-H){µ-Ph₂PCH₂(Ph₂PCH₂)₂CMe}(CO)₈], for which fluxionality of the µ₂-ligand system is reported. © 1989.

Original language	English
Pages (from-to)	C1-C4
Journal	Journal of Organometallic Chemistry
Volume	373
Issue number	1
Publication status	Published - 5 Sept 1989

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@article{ca708dd446154d2ab710e8f3243854b2,

title = "Facile cleavage of [RhRu3(μ-H)2(μ-CO)(CO)9(η5-C5H5)] with elimination of benzene on reaction with (Ph2PCH2)3CMe (triphos). Structural characterisation and non-rigidity of [Ru3(μ-H)\{μ-PPhCH2(Ph2PCH2)2CMe\}(CO)8]",

abstract = "Reaction of [RhRu3(µ-H)2(µ-CO)(CO)9(?5-C5H5)] with (Ph2PCH2)3CMe in tetrahydofuran, at or below ambient temperature, causes extensive cleavage of the cluster and intramolecular elimination of a molecule of benzene to form structurally characterised [Ru3(µ-H)\{µ-Ph2PCH2(Ph2PCH2)2CMe\}(CO)8], for which fluxionality of the µ2-ligand system is reported. {\textcopyright} 1989.",

author = "\{Le Grand\}, \{J. L.\} and Lindsell, \{W. E.\} and McCullough, \{K. J.\}",

year = "1989",

month = sep,

day = "5",

language = "English",

volume = "373",

pages = "C1--C4",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1",

}

Facile cleavage of [RhRu₃(μ-H)₂(μ-CO)(CO)₉(η⁵-C₅H₅)] with elimination of benzene on reaction with (Ph₂PCH₂)₃CMe (triphos). Structural characterisation and non-rigidity of [Ru₃(μ-H){μ-PPhCH₂(Ph₂PCH₂)₂CMe}(CO)₈]. / Le Grand, J. L.; Lindsell, W. E.; McCullough, K. J.
In: Journal of Organometallic Chemistry, Vol. 373, No. 1, 05.09.1989, p. C1-C4.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Facile cleavage of [RhRu3(μ-H)2(μ-CO)(CO)9(η5-C5H5)] with elimination of benzene on reaction with (Ph2PCH2)3CMe (triphos). Structural characterisation and non-rigidity of [Ru3(μ-H){μ-PPhCH2(Ph2PCH2)2CMe}(CO)8]

AU - Le Grand, J. L.

AU - Lindsell, W. E.

AU - McCullough, K. J.

PY - 1989/9/5

Y1 - 1989/9/5

N2 - Reaction of [RhRu3(µ-H)2(µ-CO)(CO)9(?5-C5H5)] with (Ph2PCH2)3CMe in tetrahydofuran, at or below ambient temperature, causes extensive cleavage of the cluster and intramolecular elimination of a molecule of benzene to form structurally characterised [Ru3(µ-H){µ-Ph2PCH2(Ph2PCH2)2CMe}(CO)8], for which fluxionality of the µ2-ligand system is reported. © 1989.

AB - Reaction of [RhRu3(µ-H)2(µ-CO)(CO)9(?5-C5H5)] with (Ph2PCH2)3CMe in tetrahydofuran, at or below ambient temperature, causes extensive cleavage of the cluster and intramolecular elimination of a molecule of benzene to form structurally characterised [Ru3(µ-H){µ-Ph2PCH2(Ph2PCH2)2CMe}(CO)8], for which fluxionality of the µ2-ligand system is reported. © 1989.

UR - https://www.scopus.com/pages/publications/0010201078

M3 - Article

SN - 0022-328X

VL - 373

SP - C1-C4

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Facile cleavage of [RhRu3(μ-H)2(μ-CO)(CO)9(η5-C5H5)] with elimination of benzene on reaction with (Ph2PCH2)3CMe (triphos). Structural characterisation and non-rigidity of [Ru3(μ-H){μ-PPhCH2(Ph2PCH2)2CMe}(CO)8]

Abstract

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Facile cleavage of [RhRu₃(μ-H)₂(μ-CO)(CO)₉(η⁵-C₅H₅)] with elimination of benzene on reaction with (Ph₂PCH₂)₃CMe (triphos). Structural characterisation and non-rigidity of [Ru₃(μ-H){μ-PPhCH₂(Ph₂PCH₂)₂CMe}(CO)₈]