Facile cleavage of [RhRu3(μ-H)2(μ-CO)(CO)95-C5H5)] with elimination of benzene on reaction with (Ph2PCH2)3CMe (triphos). Structural characterisation and non-rigidity of [Ru3(μ-H){μ-PPhCH2(Ph2PCH2)2CMe}(CO)8]

J. L. Le Grand, W. E. Lindsell, K. J. McCullough

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Abstract

Reaction of [RhRu3(µ-H)2(µ-CO)(CO)9(?5-C5H5)] with (Ph2PCH2)3CMe in tetrahydofuran, at or below ambient temperature, causes extensive cleavage of the cluster and intramolecular elimination of a molecule of benzene to form structurally characterised [Ru3(µ-H){µ-Ph2PCH2(Ph2PCH2)2CMe}(CO)8], for which fluxionality of the µ2-ligand system is reported. © 1989.

Original languageEnglish
Pages (from-to)C1-C4
JournalJournal of Organometallic Chemistry
Volume373
Issue number1
Publication statusPublished - 5 Sep 1989

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Carbon Monoxide
Benzene
Ligands
Molecules
Temperature

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title = "Facile cleavage of [RhRu3(μ-H)2(μ-CO)(CO)9(η5-C5H5)] with elimination of benzene on reaction with (Ph2PCH2)3CMe (triphos). Structural characterisation and non-rigidity of [Ru3(μ-H){μ-PPhCH2(Ph2PCH2)2CMe}(CO)8]",
abstract = "Reaction of [RhRu3(µ-H)2(µ-CO)(CO)9(?5-C5H5)] with (Ph2PCH2)3CMe in tetrahydofuran, at or below ambient temperature, causes extensive cleavage of the cluster and intramolecular elimination of a molecule of benzene to form structurally characterised [Ru3(µ-H){µ-Ph2PCH2(Ph2PCH2)2CMe}(CO)8], for which fluxionality of the µ2-ligand system is reported. {\circledC} 1989.",
author = "{Le Grand}, {J. L.} and Lindsell, {W. E.} and McCullough, {K. J.}",
year = "1989",
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language = "English",
volume = "373",
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TY - JOUR

T1 - Facile cleavage of [RhRu3(μ-H)2(μ-CO)(CO)9(η5-C5H5)] with elimination of benzene on reaction with (Ph2PCH2)3CMe (triphos). Structural characterisation and non-rigidity of [Ru3(μ-H){μ-PPhCH2(Ph2PCH2)2CMe}(CO)8]

AU - Le Grand, J. L.

AU - Lindsell, W. E.

AU - McCullough, K. J.

PY - 1989/9/5

Y1 - 1989/9/5

N2 - Reaction of [RhRu3(µ-H)2(µ-CO)(CO)9(?5-C5H5)] with (Ph2PCH2)3CMe in tetrahydofuran, at or below ambient temperature, causes extensive cleavage of the cluster and intramolecular elimination of a molecule of benzene to form structurally characterised [Ru3(µ-H){µ-Ph2PCH2(Ph2PCH2)2CMe}(CO)8], for which fluxionality of the µ2-ligand system is reported. © 1989.

AB - Reaction of [RhRu3(µ-H)2(µ-CO)(CO)9(?5-C5H5)] with (Ph2PCH2)3CMe in tetrahydofuran, at or below ambient temperature, causes extensive cleavage of the cluster and intramolecular elimination of a molecule of benzene to form structurally characterised [Ru3(µ-H){µ-Ph2PCH2(Ph2PCH2)2CMe}(CO)8], for which fluxionality of the µ2-ligand system is reported. © 1989.

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M3 - Article

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SP - C1-C4

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

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ER -