Fabrication of High Efficiency Flexible CIGS Solar Cell with ZnO Diffusion Barrier on Stainless Steel Substrate

Dowon Bae, Sehan Kwon, Joonjae Oh, Joowon Lee, Wookyoung Kim

Research output: Chapter in Book/Report/Conference proceedingConference contribution

6 Citations (Scopus)

Abstract

i-ZnO layers were deposited as diffusion barriers fabricated by RF sputtering on stainless-steel substrates (SUS430, matches with AISI SUS24). It was found that the addition of ZnO layer between stainless-steel substrate and Mo back contact film deplete diffusion of metal ions from substrate and reduce recombination at CIGS layer, as identified by an SIMS depth profile, QE and C-V measurements. With such diffusion barriers, the efficiency, open-circuit voltage, short-circuit current and fill factor of CIGS solar cells all increased, compared to reference cells without diffusion barrier. For the better device performance, Na was supplied during Mo back-contact layer deposition by co-sputtering of the target, including Na-source. Efficiencies of cells were increased with increasing the quantity of Na source. Unlike barrier thickness effect, short circuit current was reduced and open circuit voltage, fill factor were increased with increasing Na-source, and achieved 12.6% efficiency without AR(anti-reflection) coating. The relationship and causality between these results and the Na-doping were analyzed using C-V measurements.
Original languageEnglish
Title of host publicationCompound Semiconductors for Energy Applications and Environmental Sustainability - 2011
PublisherCambridge University Press
Pages115-120
Number of pages6
ISBN (Print)9781605113012
DOIs
Publication statusPublished - 1 Apr 2011
Event2011 MRS Spring Meeting - San Francisco, United States
Duration: 25 Apr 201129 Apr 2011

Publication series

NameMaterials Research Society Symposium Proceedings
Volume1324
ISSN (Print)0272-9172

Conference

Conference2011 MRS Spring Meeting
Country/TerritoryUnited States
CitySan Francisco
Period25/04/1129/04/11

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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