Exopolyhedral ligand flipping on isomerisation of novel supraicosahedral stannacarboranes

Peter D. Abram, David Ellis, Georgina M. Rosair, Alan J. Welch

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Novel p-block metallacarboranes with 4,1,10-SnC2B10 and 4,1,12-SnC2B10 architectures are described; the structures of bipyridyl adducts of these compounds reveal very different bipyridyl orientations yielding unique experimental information on the relative trans influences of facial B and C atoms in the cage. © The Royal Society of Chemistry 2009.

Original languageEnglish
Pages (from-to)5403-5405
Number of pages3
JournalChemical Communications
Volume2009
Issue number36
DOIs
Publication statusPublished - 28 Sep 2009

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