Exopolyhedral ligand flipping on isomerisation of novel supraicosahedral stannacarboranes

Peter D. Abram; David Ellis; Georgina M. Rosair; Alan J. Welch

doi:10.1039/b911350a

Exopolyhedral ligand flipping on isomerisation of novel supraicosahedral stannacarboranes

Peter D. Abram, David Ellis, Georgina M. Rosair, Alan J. Welch

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Novel p-block metallacarboranes with 4,1,10-SnC₂B₁₀ and 4,1,12-SnC₂B₁₀ architectures are described; the structures of bipyridyl adducts of these compounds reveal very different bipyridyl orientations yielding unique experimental information on the relative trans influences of facial B and C atoms in the cage. © The Royal Society of Chemistry 2009.

Original language	English
Pages (from-to)	5403-5405
Number of pages	3
Journal	Chemical Communications
Volume	2009
Issue number	36
DOIs	https://doi.org/10.1039/b911350a
Publication status	Published - 28 Sept 2009

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title = "Exopolyhedral ligand flipping on isomerisation of novel supraicosahedral stannacarboranes",

abstract = "Novel p-block metallacarboranes with 4,1,10-SnC2B10 and 4,1,12-SnC2B10 architectures are described; the structures of bipyridyl adducts of these compounds reveal very different bipyridyl orientations yielding unique experimental information on the relative trans influences of facial B and C atoms in the cage. {\textcopyright} The Royal Society of Chemistry 2009.",

author = "Abram, {Peter D.} and David Ellis and Rosair, {Georgina M.} and Welch, {Alan J.}",

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AU - Abram, Peter D.

AU - Ellis, David

AU - Rosair, Georgina M.

AU - Welch, Alan J.

PY - 2009/9/28

Y1 - 2009/9/28

N2 - Novel p-block metallacarboranes with 4,1,10-SnC2B10 and 4,1,12-SnC2B10 architectures are described; the structures of bipyridyl adducts of these compounds reveal very different bipyridyl orientations yielding unique experimental information on the relative trans influences of facial B and C atoms in the cage. © The Royal Society of Chemistry 2009.

AB - Novel p-block metallacarboranes with 4,1,10-SnC2B10 and 4,1,12-SnC2B10 architectures are described; the structures of bipyridyl adducts of these compounds reveal very different bipyridyl orientations yielding unique experimental information on the relative trans influences of facial B and C atoms in the cage. © The Royal Society of Chemistry 2009.

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U2 - 10.1039/b911350a

DO - 10.1039/b911350a

M3 - Article

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VL - 2009

SP - 5403

EP - 5405

JO - Chemical Communications

JF - Chemical Communications

IS - 36

ER -

Exopolyhedral ligand flipping on isomerisation of novel supraicosahedral stannacarboranes

Abstract

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