Equilibrium data and thermodynamic modelling of cyclopentane and neopentane hydrates

B. Tohidi, A. Danesh, A. C. Todd, R. W. Burgass, K. K. ØStergaard

    Research output: Contribution to journalArticlepeer-review

    108 Citations (SciVal)

    Abstract

    Cyclopentane and neopentane have only recently been recognised as a potential hydrate former, forming structure-II gas hydrates. However, no information on their hydrate phase boundary or modelling has yet been reported. In this paper, experimental hydrate dissociation data for cyclopentane and neopentane in their binaries and ternaries with methane or/and nitrogen (i.e., methane/cyclopentane, nitrogen/cyclopentane, methane/nitrogen/cyclopentane, methane/neopentane, nitrogen/neopentane, and methane/nitrogen/neopentane) over a wide range of temperature (282-301 K and 276-293 K, respectively) have been reported. The results of comparison with other newly discovered hydrate forming compounds showed that cyclopentane is the strongest hydrate promoter with neopentane in the second place. The predicted hydrate free zone is in good agreement with the experimental data, demonstrating the success of modelling. © 1997 Elsevier Science B.V.

    Original languageEnglish
    Pages (from-to)241-250
    Number of pages10
    JournalFluid Phase Equilibria
    Volume138
    Issue number1-2
    DOIs
    Publication statusPublished - Nov 1997

    Keywords

    • Application
    • Data
    • Experimental
    • Hydrates
    • Model
    • Pentanes

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