Entrapment of elusive guests within metal-seamed nanocapsules

Harshita Kumari; Ping Jin; Simon J. Teat; Charles L. Barnes; Scott J. Dalgarno; Jerry L. Atwood

doi:10.1002/anie.201406776

Entrapment of elusive guests within metal-seamed nanocapsules

Harshita Kumari
, Ping Jin
, Simon J. Teat
, Charles L. Barnes
, Scott J. Dalgarno
, Jerry L. Atwood^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Anions play a crucial role in locking alkali metals on the interior of metal-organic capsules that contain structural water gates. This role is further evidenced when stitching-up the capsule seam, resulting in either expulsion or trapping of cesium ions depending on the anion employed.

Original language	English
Pages (from-to)	13088-13092
Number of pages	5
Journal	Angewandte Chemie International Edition
Volume	53
Issue number	48
DOIs	https://doi.org/10.1002/anie.201406776
Publication status	Published - 24 Nov 2014

Keywords

Calixarenes
Cesium
Encapsulation
Ion transport
Supramolecular chemistry

ASJC Scopus subject areas

General Chemistry
Catalysis

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10.1002/anie.201406776

Cite this

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title = "Entrapment of elusive guests within metal-seamed nanocapsules",

abstract = "Anions play a crucial role in locking alkali metals on the interior of metal-organic capsules that contain structural water gates. This role is further evidenced when stitching-up the capsule seam, resulting in either expulsion or trapping of cesium ions depending on the anion employed.",

keywords = "Calixarenes, Cesium, Encapsulation, Ion transport, Supramolecular chemistry",

author = "Harshita Kumari and Ping Jin and Teat, \{Simon J.\} and Barnes, \{Charles L.\} and Dalgarno, \{Scott J.\} and Atwood, \{Jerry L.\}",

year = "2014",

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AU - Kumari, Harshita

AU - Jin, Ping

AU - Teat, Simon J.

AU - Barnes, Charles L.

AU - Dalgarno, Scott J.

AU - Atwood, Jerry L.

PY - 2014/11/24

Y1 - 2014/11/24

N2 - Anions play a crucial role in locking alkali metals on the interior of metal-organic capsules that contain structural water gates. This role is further evidenced when stitching-up the capsule seam, resulting in either expulsion or trapping of cesium ions depending on the anion employed.

AB - Anions play a crucial role in locking alkali metals on the interior of metal-organic capsules that contain structural water gates. This role is further evidenced when stitching-up the capsule seam, resulting in either expulsion or trapping of cesium ions depending on the anion employed.

KW - Calixarenes

KW - Cesium

KW - Encapsulation

KW - Ion transport

KW - Supramolecular chemistry

U2 - 10.1002/anie.201406776

DO - 10.1002/anie.201406776

M3 - Article

C2 - 25297520

AN - SCOPUS:84908081967

SN - 1433-7851

VL - 53

SP - 13088

EP - 13092

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 48

ER -

Entrapment of elusive guests within metal-seamed nanocapsules

Abstract

Keywords

ASJC Scopus subject areas

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