Enhancing strategies for the assembly of metal-organic systems with inherent cavity-containing calix[4]arenes

Piotr P Cholewa; Christine M Beavers; Simon J Teat; Scott J Dalgarno

doi:10.1021/cg4013685

Enhancing strategies for the assembly of metal-organic systems with inherent cavity-containing calix[4]arenes

Piotr P Cholewa, Christine M Beavers, Simon J Teat, Scott J Dalgarno

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

p-Carboxylatocalix[4]arenes have recently emerged as useful building blocks in the assembly of both discrete and polymeric coordination compounds. Steric effects of coligands used are now shown to dramatically influence the assembly process, dictating the assembly of one-dimensional (1D)-three-dimensional (3D) systems. Solvothermal techniques have also been found to promote formation of 3D systems with a sterically undemanding coligand.

Original language	English
Pages (from-to)	5165-5168
Number of pages	4
Journal	Crystal Growth and Design
Volume	13
Issue number	12
DOIs	https://doi.org/10.1021/cg4013685
Publication status	Published - 4 Dec 2013

Keywords

METHANE STORAGE
GAS-ADSORPTION
FUNCTIONALITY
FRAMEWORKS
HYDROGEN
DESIGN

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10.1021/cg4013685

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abstract = "p-Carboxylatocalix[4]arenes have recently emerged as useful building blocks in the assembly of both discrete and polymeric coordination compounds. Steric effects of coligands used are now shown to dramatically influence the assembly process, dictating the assembly of one-dimensional (1D)-three-dimensional (3D) systems. Solvothermal techniques have also been found to promote formation of 3D systems with a sterically undemanding coligand.",

keywords = "METHANE STORAGE, GAS-ADSORPTION, FUNCTIONALITY, FRAMEWORKS, HYDROGEN, DESIGN",

author = "Cholewa, {Piotr P} and Beavers, {Christine M} and Teat, {Simon J} and Dalgarno, {Scott J}",

year = "2013",

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doi = "10.1021/cg4013685",

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AU - Cholewa, Piotr P

AU - Beavers, Christine M

AU - Teat, Simon J

AU - Dalgarno, Scott J

PY - 2013/12/4

Y1 - 2013/12/4

N2 - p-Carboxylatocalix[4]arenes have recently emerged as useful building blocks in the assembly of both discrete and polymeric coordination compounds. Steric effects of coligands used are now shown to dramatically influence the assembly process, dictating the assembly of one-dimensional (1D)-three-dimensional (3D) systems. Solvothermal techniques have also been found to promote formation of 3D systems with a sterically undemanding coligand.

AB - p-Carboxylatocalix[4]arenes have recently emerged as useful building blocks in the assembly of both discrete and polymeric coordination compounds. Steric effects of coligands used are now shown to dramatically influence the assembly process, dictating the assembly of one-dimensional (1D)-three-dimensional (3D) systems. Solvothermal techniques have also been found to promote formation of 3D systems with a sterically undemanding coligand.

KW - METHANE STORAGE

KW - GAS-ADSORPTION

KW - FUNCTIONALITY

KW - FRAMEWORKS

KW - HYDROGEN

KW - DESIGN

U2 - 10.1021/cg4013685

DO - 10.1021/cg4013685

M3 - Article

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JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 12

ER -

Enhancing strategies for the assembly of metal-organic systems with inherent cavity-containing calix[4]arenes

Abstract

Keywords

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