Abstract
This paper examines the delamination of palladium (Pd) coatings bonded to a steel substrate under equi-biaxial compression coupled with diffusion-induced stress. The study focuses on circular delaminations. Large delaminations cause the coating to debond, forming blisters, which generate a driving force on the edge crack tip. A two-part theoretical model is developed: axisymmetric blister propagation in a stable circular pattern and non-axisymmetric perturbation of the blister leading to branching. Detailed experimental studies validate the theoretical predictions. The experiments show that non-axisymmetric crack tip instabilities during propagation result in worm-like patterns.
| Original language | English |
|---|---|
| Article number | 100876 |
| Journal | International Journal of Electrochemical Science |
| Volume | 19 |
| Issue number | 12 |
| Early online date | 18 Nov 2024 |
| DOIs | |
| Publication status | Published - Dec 2024 |
Keywords
- Circular delaminations
- Delamination
- Diffusion-induced stress
- Equi-biaxial compression
- Non-axisymmetric instabilities
- Palladium coatings
ASJC Scopus subject areas
- Electrochemistry
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