Enhanced energy conversion of up-conversion solar cells by the integration of compound parabolic concentrating optics

Georgios E. Arnaoutakis, Jose Marques-Hueso, Aruna Ivaturi, Stefan Fischer, Jan C. Goldschmidt, Karl W. Krämer, Bryce S. Richards

Research output: Contribution to journalArticle

39 Citations (Scopus)
82 Downloads (Pure)

Abstract

Up-conversion (UC) is a promising approach to utilize sub-band-gap photons for solar cells (SCs). Due to the non-linear nature of UC, the optimal excitation power regimes between the solar cell semiconductor and the UC material correspond to a difference in solar concentration of more than an order of magnitude. This difference can be bridged with integrated optics by concentrating the photons transmitted through the solar cell to increase the power density and maximize the intensity of UC luminescence. To realize this, dielectric-filled compound parabolic concentrators (CPCs) were used as integrated optics on the rear side of a planar bifacial silicon solar cell together with a 25% Er<sup>3+</sup> doped hexagonal sodium yttrium fluoride (β-NaYF<inf>4</inf>:Er) UC phosphor. An efficiency increase of 32% from 0.123% to 0.163% under sub-band-gap illumination is quantified by means of the first ever reported I-V characteristics for an up-conversion solar cell (UC-SC) based on c-Si. An enhancement in external quantum efficiency (EQE) is obtained from 1.33% for the non-concentrating reference UC-SC to 1.80% for a solar cell with integrated optics for an excitation at 1523 nm with an irradiance of 0.024 W/cm<sup>2</sup>, corresponding to a normalized EQE of 0.75 W/cm<sup>2</sup>. This demonstrates that CPCs are suitable for UC-SC as they increase the concentration in the forwards direction, while maintaining high collection efficiency of the UC emission in the reverse direction. In addition, such an approach enables the optimization of the solar concentration on the UC phosphor independently from the concentration required for the solar cell.

Original languageEnglish
Pages (from-to)217-223
Number of pages7
JournalSolar Energy Materials and Solar Cells
Volume140
DOIs
Publication statusPublished - Sep 2015

Keywords

  • Compound parabolic concentrator
  • Erbium
  • Integrated optics
  • Photovoltaics
  • Silicon
  • Up-conversion

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films

Fingerprint Dive into the research topics of 'Enhanced energy conversion of up-conversion solar cells by the integration of compound parabolic concentrating optics'. Together they form a unique fingerprint.

  • Cite this