Abstract
The dissociative charge-transfer of CO2 with H2+ and He+ is an "internal energy resonant" process. The electron-transfer produces CO2+ ions in specified electronic states and the probability of forming these states varies with the translational energy of the reactant. Thus both the total cross-section for charge-transfer, and the relative abundances of the fragment ions show a considerable variation with reactant-ion translational energy. Fluorescence spectra of CO2+ have been obtained for reactant-ion translational energies of 2000-4500 eV. © 1977.
Original language | English |
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Pages (from-to) | 429-445 |
Number of pages | 17 |
Journal | International Journal of Mass Spectrometry and Ion Physics |
Volume | 24 |
Issue number | 4 |
Publication status | Published - Aug 1977 |