Energy transfer and primary product ion excitation in He+/CO2 and H2+/CO2 charge-transfer collisions

J. E. Parker, R. G. Milner, Alasdair Robertson

Research output: Contribution to journalArticle

Abstract

The dissociative charge-transfer of CO2 with H2+ and He+ is an "internal energy resonant" process. The electron-transfer produces CO2+ ions in specified electronic states and the probability of forming these states varies with the translational energy of the reactant. Thus both the total cross-section for charge-transfer, and the relative abundances of the fragment ions show a considerable variation with reactant-ion translational energy. Fluorescence spectra of CO2+ have been obtained for reactant-ion translational energies of 2000-4500 eV. © 1977.

Original languageEnglish
Pages (from-to)429-445
Number of pages17
JournalInternational Journal of Mass Spectrometry and Ion Physics
Volume24
Issue number4
Publication statusPublished - Aug 1977

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