Electron spin resonance studies of bis(η-cyclopentadienyl) compounds of molybdenum and tungsten

W. Edward Lindsell

Research output: Contribution to journalArticle

Abstract

A series of cations of the general formula [M(cp)2(X)Y]+ (M = Mo or W; X and Y are equivalent to uninegative unidentate ligands; cp = ?-cyclopentadienyl), have been produced by oxidation with chemical oxidants, by electrolysis, or by exchange reactions. The e.s.r. spectra of these paramagnetic species have been studied in solution and the values and solution hyperfine coupling constants are discussed. Spectra of glasses of some of the cations are also presented.

Original languageEnglish
Pages (from-to)2548-2552
Number of pages5
JournalJournal of the Chemical Society, Dalton Transactions
Issue number23
DOIs
Publication statusPublished - 1975

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