TY - JOUR
T1 - Electron spin resonance studies of bis(η-cyclopentadienyl) compounds of molybdenum and tungsten
AU - Lindsell, W. Edward
PY - 1975
Y1 - 1975
N2 - A series of cations of the general formula [M(cp)2(X)Y]+ (M = Mo or W; X and Y are equivalent to uninegative unidentate ligands; cp = ?-cyclopentadienyl), have been produced by oxidation with chemical oxidants, by electrolysis, or by exchange reactions. The e.s.r. spectra of these paramagnetic species have been studied in solution and the values and solution hyperfine coupling constants are discussed. Spectra of glasses of some of the cations are also presented.
AB - A series of cations of the general formula [M(cp)2(X)Y]+ (M = Mo or W; X and Y are equivalent to uninegative unidentate ligands; cp = ?-cyclopentadienyl), have been produced by oxidation with chemical oxidants, by electrolysis, or by exchange reactions. The e.s.r. spectra of these paramagnetic species have been studied in solution and the values and solution hyperfine coupling constants are discussed. Spectra of glasses of some of the cations are also presented.
UR - http://www.scopus.com/inward/record.url?scp=37049126046&partnerID=8YFLogxK
U2 - 10.1039/DT9750002548
DO - 10.1039/DT9750002548
M3 - Article
SN - 1472-7773
SP - 2548
EP - 2552
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
IS - 23
ER -