Dynamic studies of poly(di-n-alkyl itaconate)s

V. Arrighi; P. F. Holmes; S. Gagliardi; I. J. McEwen; M. T F Telling

doi:10.1007/s003390201345

Dynamic studies of poly(di-n-alkyl itaconate)s

V. Arrighi, P. F. Holmes, S. Gagliardi, I. J. McEwen, M. T F Telling

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

We report a preliminary dynamic study of poly(di-n-alkyl itaconate)s with varying side chain length n. QENS measurements were carried out on two backscattering spectrometers, IRIS at ISIS and IN10 at the ILL in the temperature range of 4 to 350 K. We show that molecular motion can be detected well below the polymer glass transition for all samples. It is possible to distinguish different dynamic processes. The temperature range over which these are observed is dependent on the length of the side chain, n. The intermediate scattering function, I(Q, t), was determined from the IRIS and found to obey time-temperature superposition. We show that the I(Q, t) data at different temperatures can be overlapped using the same time-scale shift factors, indicating that the relaxation process is common to all the polymers investigated.

Original language	English
Pages (from-to)	S466-S468
Journal	Applied Physics A: Materials Science and Processing
Volume	74
Issue number	SUPPL.I
DOIs	https://doi.org/10.1007/s003390201345
Publication status	Published - Dec 2002

Access to Document

10.1007/s003390201345

Cite this

@article{c4aee14a638c4e7cbfd5cb1049e6a850,

title = "Dynamic studies of poly(di-n-alkyl itaconate)s",

abstract = "We report a preliminary dynamic study of poly(di-n-alkyl itaconate)s with varying side chain length n. QENS measurements were carried out on two backscattering spectrometers, IRIS at ISIS and IN10 at the ILL in the temperature range of 4 to 350 K. We show that molecular motion can be detected well below the polymer glass transition for all samples. It is possible to distinguish different dynamic processes. The temperature range over which these are observed is dependent on the length of the side chain, n. The intermediate scattering function, I(Q, t), was determined from the IRIS and found to obey time-temperature superposition. We show that the I(Q, t) data at different temperatures can be overlapped using the same time-scale shift factors, indicating that the relaxation process is common to all the polymers investigated.",

author = "V. Arrighi and Holmes, {P. F.} and S. Gagliardi and McEwen, {I. J.} and Telling, {M. T F}",

year = "2002",

month = dec,

doi = "10.1007/s003390201345",

language = "English",

volume = "74",

pages = "S466--S468",

journal = "Applied Physics A: Materials Science and Processing",

issn = "1432-0630",

publisher = "Springer",

number = "SUPPL.I",

}

TY - JOUR

T1 - Dynamic studies of poly(di-n-alkyl itaconate)s

AU - Arrighi, V.

AU - Holmes, P. F.

AU - Gagliardi, S.

AU - McEwen, I. J.

AU - Telling, M. T F

PY - 2002/12

Y1 - 2002/12

N2 - We report a preliminary dynamic study of poly(di-n-alkyl itaconate)s with varying side chain length n. QENS measurements were carried out on two backscattering spectrometers, IRIS at ISIS and IN10 at the ILL in the temperature range of 4 to 350 K. We show that molecular motion can be detected well below the polymer glass transition for all samples. It is possible to distinguish different dynamic processes. The temperature range over which these are observed is dependent on the length of the side chain, n. The intermediate scattering function, I(Q, t), was determined from the IRIS and found to obey time-temperature superposition. We show that the I(Q, t) data at different temperatures can be overlapped using the same time-scale shift factors, indicating that the relaxation process is common to all the polymers investigated.

AB - We report a preliminary dynamic study of poly(di-n-alkyl itaconate)s with varying side chain length n. QENS measurements were carried out on two backscattering spectrometers, IRIS at ISIS and IN10 at the ILL in the temperature range of 4 to 350 K. We show that molecular motion can be detected well below the polymer glass transition for all samples. It is possible to distinguish different dynamic processes. The temperature range over which these are observed is dependent on the length of the side chain, n. The intermediate scattering function, I(Q, t), was determined from the IRIS and found to obey time-temperature superposition. We show that the I(Q, t) data at different temperatures can be overlapped using the same time-scale shift factors, indicating that the relaxation process is common to all the polymers investigated.

UR - http://www.scopus.com/inward/record.url?scp=0037001717&partnerID=8YFLogxK

U2 - 10.1007/s003390201345

DO - 10.1007/s003390201345

M3 - Article

SN - 1432-0630

VL - 74

SP - S466-S468

JO - Applied Physics A: Materials Science and Processing

JF - Applied Physics A: Materials Science and Processing

IS - SUPPL.I

ER -

Dynamic studies of poly(di-n-alkyl itaconate)s

Abstract

Access to Document

Other files and links

Fingerprint

Cite this