Droplet reactors with catalytic interfaces: An active fluorous phase for segmented-flow microfluidic reactions

Ashleigh B. Theberge; Graeme Whyte; Max Frenzel; Luis M. Fidalgo; Robert C. R. Wootton; Wilhelm T. S. Huck

Droplet reactors with catalytic interfaces: An active fluorous phase for segmented-flow microfluidic reactions

Ashleigh B. Theberge, Graeme Whyte, Max Frenzel, Luis M. Fidalgo, Robert C. R. Wootton, Wilhelm T. S. Huck

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

By combining droplet-based microfluidics with fluorous biphasic catalysis, we generated droplet reactors with catalytically active walls and used these compartments as a tool for organic synthesis. Our approach provides a closed-loop system for catalyst recycling, controlled catalytic reaction compartments, and the opportunity for facile on-line optimization.

Original language	English
Title of host publication	Proceedings of the 13th International Conference on Miniaturized Systems for Chemistry and Life Sciences
Publisher	Chemical and Biological Microsystems Society
Pages	12-14
Number of pages	3
ISBN (Print)	9780979806421
Publication status	Published - 2009
Event	13th International Conference on Miniaturized Systems for Chemistry and Life Sciences 2009 - Jeju, Korea, Republic of Duration: 1 Nov 2009 → 5 Nov 2009

Conference

Conference	13th International Conference on Miniaturized Systems for Chemistry and Life Sciences 2009
Abbreviated title	MicroTAS 2009
Country/Territory	Korea, Republic of
City	Jeju
Period	1/11/09 → 5/11/09

Keywords

Fluorous biphasic catalysis
Green chemistry
Microdroplets
Suzuki-Miyaura coupling

ASJC Scopus subject areas

Chemical Engineering (miscellaneous)
Bioengineering

Cite this

Theberge, A. B., Whyte, G., Frenzel, M., Fidalgo, L. M., Wootton, R. C. R., & Huck, W. T. S. (2009). Droplet reactors with catalytic interfaces: An active fluorous phase for segmented-flow microfluidic reactions. In Proceedings of the 13th International Conference on Miniaturized Systems for Chemistry and Life Sciences (pp. 12-14). Chemical and Biological Microsystems Society.

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title = "Droplet reactors with catalytic interfaces: An active fluorous phase for segmented-flow microfluidic reactions",

abstract = "By combining droplet-based microfluidics with fluorous biphasic catalysis, we generated droplet reactors with catalytically active walls and used these compartments as a tool for organic synthesis. Our approach provides a closed-loop system for catalyst recycling, controlled catalytic reaction compartments, and the opportunity for facile on-line optimization.",

keywords = "Fluorous biphasic catalysis, Green chemistry, Microdroplets, Suzuki-Miyaura coupling",

author = "Theberge, {Ashleigh B.} and Graeme Whyte and Max Frenzel and Fidalgo, {Luis M.} and Wootton, {Robert C. R.} and Huck, {Wilhelm T. S.}",

year = "2009",

language = "English",

isbn = "9780979806421",

pages = "12--14",

booktitle = "Proceedings of the 13th International Conference on Miniaturized Systems for Chemistry and Life Sciences",

publisher = "Chemical and Biological Microsystems Society",

note = "13th International Conference on Miniaturized Systems for Chemistry and Life Sciences 2009, MicroTAS 2009 ; Conference date: 01-11-2009 Through 05-11-2009",

}

Theberge, AB, Whyte, G, Frenzel, M, Fidalgo, LM, Wootton, RCR & Huck, WTS 2009, Droplet reactors with catalytic interfaces: An active fluorous phase for segmented-flow microfluidic reactions. in Proceedings of the 13th International Conference on Miniaturized Systems for Chemistry and Life Sciences. Chemical and Biological Microsystems Society, pp. 12-14, 13th International Conference on Miniaturized Systems for Chemistry and Life Sciences 2009, Jeju, Korea, Republic of, 1/11/09.

Droplet reactors with catalytic interfaces: An active fluorous phase for segmented-flow microfluidic reactions. / Theberge, Ashleigh B.; Whyte, Graeme; Frenzel, Max et al.
Proceedings of the 13th International Conference on Miniaturized Systems for Chemistry and Life Sciences. Chemical and Biological Microsystems Society, 2009. p. 12-14.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

TY - GEN

T1 - Droplet reactors with catalytic interfaces

T2 - 13th International Conference on Miniaturized Systems for Chemistry and Life Sciences 2009

AU - Theberge, Ashleigh B.

AU - Whyte, Graeme

AU - Frenzel, Max

AU - Fidalgo, Luis M.

AU - Wootton, Robert C. R.

AU - Huck, Wilhelm T. S.

PY - 2009

Y1 - 2009

N2 - By combining droplet-based microfluidics with fluorous biphasic catalysis, we generated droplet reactors with catalytically active walls and used these compartments as a tool for organic synthesis. Our approach provides a closed-loop system for catalyst recycling, controlled catalytic reaction compartments, and the opportunity for facile on-line optimization.

AB - By combining droplet-based microfluidics with fluorous biphasic catalysis, we generated droplet reactors with catalytically active walls and used these compartments as a tool for organic synthesis. Our approach provides a closed-loop system for catalyst recycling, controlled catalytic reaction compartments, and the opportunity for facile on-line optimization.

KW - Fluorous biphasic catalysis

KW - Green chemistry

KW - Microdroplets

KW - Suzuki-Miyaura coupling

UR - http://www.scopus.com/inward/record.url?scp=84901756975&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:84901756975

SN - 9780979806421

SP - 12

EP - 14

BT - Proceedings of the 13th International Conference on Miniaturized Systems for Chemistry and Life Sciences

PB - Chemical and Biological Microsystems Society

Y2 - 1 November 2009 through 5 November 2009

ER -

Droplet reactors with catalytic interfaces: An active fluorous phase for segmented-flow microfluidic reactions

Abstract

Conference

Keywords

ASJC Scopus subject areas

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