TY - JOUR
T1 - Double insertion of a platinum nucleophile into a closo-carbaborane: molecular structures of 4,4-(Et3P)2-1,7-Me2-1,4,7-CPtCB5H5 and 1,1-(Et3P)2-6,6-(Et3P)2-4,5-Me2-1,4,5,6-PtC2PtB5H5
AU - Barker, Geoffrey K.
AU - Garcia, Maria P.
AU - Green, Michael
AU - Stone, F. Gordon A.
AU - Welch, Alan J.
PY - 1982
Y1 - 1982
N2 - The carbaboranes closo-2,4-R2-2,4-C2B 5H5 (R = H or Me) react with [Pt2(μ-cod) (PEt3)4] (cod = cyclo-octa-1,5-diene) to afford the carbaplatinaboranes 4,4-(Et3P)2-1,7-R2-1,4,7- CPtCB5H5 and 1,1-(Et3P)2-6,6- (Et3P)2-4,5-Me2-1,4,5,6-PtC2PtB 5H5; the molecular structures of the two methyl derivatives have been established by X-ray diffraction.
AB - The carbaboranes closo-2,4-R2-2,4-C2B 5H5 (R = H or Me) react with [Pt2(μ-cod) (PEt3)4] (cod = cyclo-octa-1,5-diene) to afford the carbaplatinaboranes 4,4-(Et3P)2-1,7-R2-1,4,7- CPtCB5H5 and 1,1-(Et3P)2-6,6- (Et3P)2-4,5-Me2-1,4,5,6-PtC2PtB 5H5; the molecular structures of the two methyl derivatives have been established by X-ray diffraction.
UR - http://www.scopus.com/inward/record.url?scp=37049111655&partnerID=8YFLogxK
U2 - 10.1039/C39820000046
DO - 10.1039/C39820000046
M3 - Article
SN - 0022-4936
SP - 46
EP - 48
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 1
ER -