Diphosphaborane and Metalladiphosphaborane: Ligands for Transition-Metal Chemistry

Ross McLellan; David Ellis; Georgina Margaret Rosair; Alan Jeffrey Welch

doi:10.1002/anie.201105820

Diphosphaborane and Metalladiphosphaborane: Ligands for Transition-Metal Chemistry

Ross McLellan, David Ellis, Georgina Margaret Rosair, Alan Jeffrey Welch

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

New ligands: The first examples of a neutral heteroborane and a neutral metallaheteroborane acting as simple s-bound ligands to transition metals are described. In [HCo(1,2-closo-P2B10H10)2(PEt3)2] (see structure, left) the P2B10H10 ligand coordinates to Co through one P atom, and in µ-[1,2-{HRu(p cymene)}2-7',8'-nido-P2B9H9]-3-(p-cymene)-3,1,2-closo-RuP2B9H9 (right) both closo-RuP2B9 and nido-P2B9 cages act as bridging ?P:?P' ligands.

Original language	English
Pages (from-to)	12339-12341
Number of pages	3
Journal	Angewandte Chemie International Edition
Volume	50
Issue number	51
DOIs	https://doi.org/10.1002/anie.201105820
Publication status	Published - 16 Dec 2011

Keywords

boron
diphosphaboranes
metalladiphosphaboranes
transition-metal complexes

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10.1002/anie.201105820

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title = "Diphosphaborane and Metalladiphosphaborane: Ligands for Transition-Metal Chemistry",

abstract = "New ligands: The first examples of a neutral heteroborane and a neutral metallaheteroborane acting as simple s-bound ligands to transition metals are described. In [HCo(1,2-closo-P2B10H10)2(PEt3)2] (see structure, left) the P2B10H10 ligand coordinates to Co through one P atom, and in µ-[1,2-{HRu(p cymene)}2-7',8'-nido-P2B9H9]-3-(p-cymene)-3,1,2-closo-RuP2B9H9 (right) both closo-RuP2B9 and nido-P2B9 cages act as bridging ?P:?P' ligands.",

keywords = "boron, diphosphaboranes, metalladiphosphaboranes, transition-metal complexes",

author = "Ross McLellan and David Ellis and Rosair, {Georgina Margaret} and Welch, {Alan Jeffrey}",

year = "2011",

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day = "16",

doi = "10.1002/anie.201105820",

language = "English",

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journal = "Angewandte Chemie International Edition",

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publisher = "John Wiley and Sons Ltd",

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TY - JOUR

T1 - Diphosphaborane and Metalladiphosphaborane: Ligands for Transition-Metal Chemistry

AU - McLellan, Ross

AU - Ellis, David

AU - Rosair, Georgina Margaret

AU - Welch, Alan Jeffrey

PY - 2011/12/16

Y1 - 2011/12/16

N2 - New ligands: The first examples of a neutral heteroborane and a neutral metallaheteroborane acting as simple s-bound ligands to transition metals are described. In [HCo(1,2-closo-P2B10H10)2(PEt3)2] (see structure, left) the P2B10H10 ligand coordinates to Co through one P atom, and in µ-[1,2-{HRu(p cymene)}2-7',8'-nido-P2B9H9]-3-(p-cymene)-3,1,2-closo-RuP2B9H9 (right) both closo-RuP2B9 and nido-P2B9 cages act as bridging ?P:?P' ligands.

AB - New ligands: The first examples of a neutral heteroborane and a neutral metallaheteroborane acting as simple s-bound ligands to transition metals are described. In [HCo(1,2-closo-P2B10H10)2(PEt3)2] (see structure, left) the P2B10H10 ligand coordinates to Co through one P atom, and in µ-[1,2-{HRu(p cymene)}2-7',8'-nido-P2B9H9]-3-(p-cymene)-3,1,2-closo-RuP2B9H9 (right) both closo-RuP2B9 and nido-P2B9 cages act as bridging ?P:?P' ligands.

KW - boron

KW - diphosphaboranes

KW - metalladiphosphaboranes

KW - transition-metal complexes

U2 - 10.1002/anie.201105820

DO - 10.1002/anie.201105820

M3 - Article

C2 - 22025332

AN - SCOPUS:83755184139

SN - 1433-7851

VL - 50

SP - 12339

EP - 12341

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 51

ER -

Diphosphaborane and Metalladiphosphaborane: Ligands for Transition-Metal Chemistry

Abstract

Keywords

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