Definitive crystal structure of 1,1'-bis[1,2-dicarba-closo-dodecaborane(11)]

Wing Man; Georgina Margaret Rosair; Alan Jeffrey Welch

doi:10.1107/S1600536814023897

Definitive crystal structure of 1,1'-bis[1,2-dicarba-closo-dodecaborane(11)]

Wing Man, Georgina Margaret Rosair, Alan Jeffrey Welch

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10 Citations (Scopus)

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Abstract

In the title compound, C4H22B20, the two {1,2-closo-C2B10H11} cages are linked across a centre of inversion with a C–C distance of 1.5339 (11) Å. By careful analysis of the structure, it is established that the non-linking cage C atom is equally disordered over cage vertices 2 and 3.

Original language	English
Pages (from-to)	462-465
Number of pages	4
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	70
Issue number	12
DOIs	https://doi.org/10.1107/S1600536814023897
Publication status	Published - Dec 2014

Keywords

crystal structure
carboranes
1,2-dicarba-closo-dodecaborane(11)
cage compounds

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title = "Definitive crystal structure of 1,1'-bis[1,2-dicarba-closo-dodecaborane(11)]",

abstract = "In the title compound, C4H22B20, the two {1,2-closo-C2B10H11} cages are linked across a centre of inversion with a C–C distance of 1.5339 (11) {\AA}. By careful analysis of the structure, it is established that the non-linking cage C atom is equally disordered over cage vertices 2 and 3.",

keywords = "crystal structure, carboranes, 1,2-dicarba-closo-dodecaborane(11), cage compounds",

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pages = "462--465",

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T1 - Definitive crystal structure of 1,1'-bis[1,2-dicarba-closo-dodecaborane(11)]

AU - Man, Wing

AU - Rosair, Georgina Margaret

AU - Welch, Alan Jeffrey

PY - 2014/12

Y1 - 2014/12

N2 - In the title compound, C4H22B20, the two {1,2-closo-C2B10H11} cages are linked across a centre of inversion with a C–C distance of 1.5339 (11) Å. By careful analysis of the structure, it is established that the non-linking cage C atom is equally disordered over cage vertices 2 and 3.

AB - In the title compound, C4H22B20, the two {1,2-closo-C2B10H11} cages are linked across a centre of inversion with a C–C distance of 1.5339 (11) Å. By careful analysis of the structure, it is established that the non-linking cage C atom is equally disordered over cage vertices 2 and 3.

KW - crystal structure

KW - carboranes

KW - 1,2-dicarba-closo-dodecaborane(11)

KW - cage compounds

U2 - 10.1107/S1600536814023897

DO - 10.1107/S1600536814023897

M3 - Article

C2 - 25552965

VL - 70

SP - 462

EP - 465

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 12

ER -

Definitive crystal structure of 1,1'-bis[1,2-dicarba-closo-dodecaborane(11)]

Abstract

Keywords

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