Definitive crystal structure of 1,1'-bis[1,2-dicarba-closo-dodecaborane(11)]

Wing Man; Georgina Margaret Rosair; Alan Jeffrey Welch

doi:10.1107/S1600536814023897

Definitive crystal structure of 1,1'-bis[1,2-dicarba-closo-dodecaborane(11)]

Wing Man, Georgina Margaret Rosair, Alan Jeffrey Welch

Research output: Contribution to journal › Article

10 Citations (Scopus)

25 Downloads (Pure)

Abstract

In the title compound, C4H22B20, the two {1,2-closo-C2B10H11} cages are linked across a centre of inversion with a C–C distance of 1.5339 (11) Å. By careful analysis of the structure, it is established that the non-linking cage C atom is equally disordered over cage vertices 2 and 3.

Original language	English
Pages (from-to)	462-465
Number of pages	4
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	70
Issue number	12
DOIs	https://doi.org/10.1107/S1600536814023897
Publication status	Published - Dec 2014

Keywords

crystal structure
carboranes
1,2-dicarba-closo-dodecaborane(11)
cage compounds

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Man, W., Rosair, G. M., & Welch, A. J. (2014). Definitive crystal structure of 1,1'-bis[1,2-dicarba-closo-dodecaborane(11)]. Acta Crystallographica Section E: Structure Reports Online, 70(12), 462-465. https://doi.org/10.1107/S1600536814023897

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KW - 1,2-dicarba-closo-dodecaborane(11)

KW - cage compounds

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