Defect clustering in lisicon solid electrolytes

P. G. Bruce; I. Abrahams; A. R. West

Defect clustering in lisicon solid electrolytes

P. G. Bruce, I. Abrahams, A. R. West

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

LISICON, Li_(2+2x)Zn_(1-x)GeO₄, is a lithium ion conducting solid solution in which the interstitial ions are ordered defect clusters. Changes in the nature of the defect clusters with temperature for one member of the solid solution series Li₃Zn_0.5GeO₄ (x=0.5), have been determined by powder neutron diffraction up to 500°C. These changes may explain curvature in the log s versus 1/T plots and the anomalously high pre-exponential factors observed at low temperatures. © 1990.

Original language	English
Pages (from-to)	293-299
Number of pages	7
Journal	Solid State Ionics
Volume	40-41
Issue number	PART 1
Publication status	Published - Aug 1990

Cite this

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title = "Defect clustering in lisicon solid electrolytes",

abstract = "LISICON, Li(2+2x)Zn(1-x)GeO4, is a lithium ion conducting solid solution in which the interstitial ions are ordered defect clusters. Changes in the nature of the defect clusters with temperature for one member of the solid solution series Li3Zn0.5GeO4 (x=0.5), have been determined by powder neutron diffraction up to 500°C. These changes may explain curvature in the log s versus 1/T plots and the anomalously high pre-exponential factors observed at low temperatures. {\textcopyright} 1990.",

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year = "1990",

month = aug,

language = "English",

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journal = "Solid State Ionics",

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T1 - Defect clustering in lisicon solid electrolytes

AU - Bruce, P. G.

AU - Abrahams, I.

AU - West, A. R.

PY - 1990/8

Y1 - 1990/8

N2 - LISICON, Li(2+2x)Zn(1-x)GeO4, is a lithium ion conducting solid solution in which the interstitial ions are ordered defect clusters. Changes in the nature of the defect clusters with temperature for one member of the solid solution series Li3Zn0.5GeO4 (x=0.5), have been determined by powder neutron diffraction up to 500°C. These changes may explain curvature in the log s versus 1/T plots and the anomalously high pre-exponential factors observed at low temperatures. © 1990.

AB - LISICON, Li(2+2x)Zn(1-x)GeO4, is a lithium ion conducting solid solution in which the interstitial ions are ordered defect clusters. Changes in the nature of the defect clusters with temperature for one member of the solid solution series Li3Zn0.5GeO4 (x=0.5), have been determined by powder neutron diffraction up to 500°C. These changes may explain curvature in the log s versus 1/T plots and the anomalously high pre-exponential factors observed at low temperatures. © 1990.

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M3 - Article

SN - 0167-2738

VL - 40-41

SP - 293

EP - 299

JO - Solid State Ionics

JF - Solid State Ionics

IS - PART 1

ER -

Defect clustering in lisicon solid electrolytes

Abstract

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