Cyclophetatrienylmolybdenum complexes. Part 3 [1]. Reaction of the cation [Mo(acac)(H2O(η7-C7H7)]+ with halide and thiocyanate anions; molecular and crystal structure of [Mo(acac)(NCS)(η7C7H7)]

M. Green; H. P. Kirsch; F. G. A. Stone; A. J. Welch

doi:10.1016/S0020-1693(00)89633-4

Cyclophetatrienylmolybdenum complexes. Part 3 [1]. Reaction of the cation [Mo(acac)(H₂O(η⁷-C₇H₇)]⁺ with halide and thiocyanate anions; molecular and crystal structure of [Mo(acac)(NCS)(η⁷C₇H₇)]

M. Green, H. P. Kirsch, F. G. A. Stone, A. J. Welch

Research output: Contribution to journal › Article › peer-review

Abstract

The complex [Mo(acac)(H₂O)(η⁷-C₇H₇)]BF₄ reacts with anionic nucleophiles to form neutral seventeen-electron paramagnetic compounds [Mp(acac)X(η⁷-C₇H₇)] (X = Cl, Br, I or NCS). Crystals of the thiocyanic derivative are monoclinic, space group P2₁/a with a = 12.762(2), b = 12.634(4) and c = 8.813(3) Å, β = 100.70(2)°; 2788 data ≥ 1.0σ have been employed to solve and refine the structure to a conventional R = 0.069. The molecule is almost identical with that of the cation [Mo(acac)(H₂O)(η⁷-C₇H₇)]⁺ with a non-linear N-bonded thiocyanate function replacing the water molecule at MoN 2.122(10) Å.

Original language	English
Pages (from-to)	101-106
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	29
DOIs	https://doi.org/10.1016/S0020-1693(00)89633-4
Publication status	Published - 1978

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{443e9b9b62db454ebb2f1ac659c34311,

title = "Cyclophetatrienylmolybdenum complexes. Part 3 [1]. Reaction of the cation [Mo(acac)(H2O(η7-C7H7)]+ with halide and thiocyanate anions; molecular and crystal structure of [Mo(acac)(NCS)(η7C7H7)]",

abstract = "The complex [Mo(acac)(H2O)(η7-C7H7)]BF4 reacts with anionic nucleophiles to form neutral seventeen-electron paramagnetic compounds [Mp(acac)X(η7-C7H7)] (X = Cl, Br, I or NCS). Crystals of the thiocyanic derivative are monoclinic, space group P21/a with a = 12.762(2), b = 12.634(4) and c = 8.813(3) {\AA}, β = 100.70(2)°; 2788 data ≥ 1.0σ have been employed to solve and refine the structure to a conventional R = 0.069. The molecule is almost identical with that of the cation [Mo(acac)(H2O)(η7-C7H7)]+ with a non-linear N-bonded thiocyanate function replacing the water molecule at MoN 2.122(10) {\AA}.",

author = "M. Green and Kirsch, {H. P.} and Stone, {F. G. A.} and Welch, {A. J.}",

year = "1978",

doi = "10.1016/S0020-1693(00)89633-4",

language = "English",

volume = "29",

pages = "101--106",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

}

Cyclophetatrienylmolybdenum complexes. Part 3 [1]. Reaction of the cation [Mo(acac)(H₂O(η⁷-C₇H₇)]⁺ with halide and thiocyanate anions; molecular and crystal structure of [Mo(acac)(NCS)(η⁷C₇H₇)]. / Green, M.; Kirsch, H. P.; Stone, F. G. A.; Welch, A. J.

In: Inorganica Chimica Acta, Vol. 29, 1978, p. 101-106.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Cyclophetatrienylmolybdenum complexes. Part 3 [1]. Reaction of the cation [Mo(acac)(H2O(η7-C7H7)]+ with halide and thiocyanate anions; molecular and crystal structure of [Mo(acac)(NCS)(η7C7H7)]

AU - Green, M.

AU - Kirsch, H. P.

AU - Stone, F. G. A.

AU - Welch, A. J.

PY - 1978

Y1 - 1978

N2 - The complex [Mo(acac)(H2O)(η7-C7H7)]BF4 reacts with anionic nucleophiles to form neutral seventeen-electron paramagnetic compounds [Mp(acac)X(η7-C7H7)] (X = Cl, Br, I or NCS). Crystals of the thiocyanic derivative are monoclinic, space group P21/a with a = 12.762(2), b = 12.634(4) and c = 8.813(3) Å, β = 100.70(2)°; 2788 data ≥ 1.0σ have been employed to solve and refine the structure to a conventional R = 0.069. The molecule is almost identical with that of the cation [Mo(acac)(H2O)(η7-C7H7)]+ with a non-linear N-bonded thiocyanate function replacing the water molecule at MoN 2.122(10) Å.

AB - The complex [Mo(acac)(H2O)(η7-C7H7)]BF4 reacts with anionic nucleophiles to form neutral seventeen-electron paramagnetic compounds [Mp(acac)X(η7-C7H7)] (X = Cl, Br, I or NCS). Crystals of the thiocyanic derivative are monoclinic, space group P21/a with a = 12.762(2), b = 12.634(4) and c = 8.813(3) Å, β = 100.70(2)°; 2788 data ≥ 1.0σ have been employed to solve and refine the structure to a conventional R = 0.069. The molecule is almost identical with that of the cation [Mo(acac)(H2O)(η7-C7H7)]+ with a non-linear N-bonded thiocyanate function replacing the water molecule at MoN 2.122(10) Å.

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U2 - 10.1016/S0020-1693(00)89633-4

DO - 10.1016/S0020-1693(00)89633-4

M3 - Article

AN - SCOPUS:49349134008

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JO - Inorganica Chimica Acta

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