TY - JOUR
T1 - Cyclophetatrienylmolybdenum complexes. Part 3 [1]. Reaction of the cation [Mo(acac)(H2O(η7-C7H7)]+ with halide and thiocyanate anions; molecular and crystal structure of [Mo(acac)(NCS)(η7C7H7)]
AU - Green, M.
AU - Kirsch, H. P.
AU - Stone, F. G. A.
AU - Welch, A. J.
PY - 1978
Y1 - 1978
N2 - The complex [Mo(acac)(H2O)(η7-C7H7)]BF4 reacts with anionic nucleophiles to form neutral seventeen-electron paramagnetic compounds [Mp(acac)X(η7-C7H7)] (X = Cl, Br, I or NCS). Crystals of the thiocyanic derivative are monoclinic, space group P21/a with a = 12.762(2), b = 12.634(4) and c = 8.813(3) Å, β = 100.70(2)°; 2788 data ≥ 1.0σ have been employed to solve and refine the structure to a conventional R = 0.069. The molecule is almost identical with that of the cation [Mo(acac)(H2O)(η7-C7H7)]+ with a non-linear N-bonded thiocyanate function replacing the water molecule at MoN 2.122(10) Å.
AB - The complex [Mo(acac)(H2O)(η7-C7H7)]BF4 reacts with anionic nucleophiles to form neutral seventeen-electron paramagnetic compounds [Mp(acac)X(η7-C7H7)] (X = Cl, Br, I or NCS). Crystals of the thiocyanic derivative are monoclinic, space group P21/a with a = 12.762(2), b = 12.634(4) and c = 8.813(3) Å, β = 100.70(2)°; 2788 data ≥ 1.0σ have been employed to solve and refine the structure to a conventional R = 0.069. The molecule is almost identical with that of the cation [Mo(acac)(H2O)(η7-C7H7)]+ with a non-linear N-bonded thiocyanate function replacing the water molecule at MoN 2.122(10) Å.
UR - http://www.scopus.com/inward/record.url?scp=49349134008&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(00)89633-4
DO - 10.1016/S0020-1693(00)89633-4
M3 - Article
AN - SCOPUS:49349134008
VL - 29
SP - 101
EP - 106
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
ER -