Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC6F5)2L2Cp] (L = SC6F5 or CO)

W. Azalee Wan Abu Bakar; Jack L. Davidson; W. Edward Lindsell; Kevin J. McCullough; Kenneth W. Muir

Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC₆F₅)₂L₂Cp] (L = SC₆F₅ or CO)

W. Azalee Wan Abu Bakar
, Jack L. Davidson
, W. Edward Lindsell
, Kevin J. McCullough
, Kenneth W. Muir

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

New bimetallic complexes [MTl(SC₆F₅)₂L₂Cp] (L = SC₆F₅, M = Mo (1a), W (1b); L = CO, M = Mo (4)) are characterised; crystal structures of 1a and 4 show unusual polydentate coordination of thallium(I) by [Mo(SC₆F₅)₂L₂Cp)]^- and var. temp. ¹⁹F NMR studies, supported by conductivity measurements and cation exchange, indicate restricted rotation of C₆F₅ groups and reversible decoordination of Tl⁺ in more polar solvents. © 1987.

Original language	English
Pages (from-to)	C1-C6
Journal	Journal of Organometallic Chemistry
Volume	322
Issue number	1
Publication status	Published - 17 Mar 1987

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Azalee Wan Abu Bakar, W., Davidson, J. L., Lindsell, W. E., McCullough, K. J., & Muir, K. W. (1987). Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC₆F₅)₂L₂Cp] (L = SC₆F₅ or CO). Journal of Organometallic Chemistry, 322(1), C1-C6.

Azalee Wan Abu Bakar, W. ; Davidson, Jack L. ; Lindsell, W. Edward et al. / Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC₆F₅)₂L₂Cp] (L = SC₆F₅ or CO). In: Journal of Organometallic Chemistry. 1987 ; Vol. 322, No. 1. pp. C1-C6.

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title = "Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC6F5)2L2Cp] (L = SC6F5 or CO)",

abstract = "New bimetallic complexes [MTl(SC6F5)2L2Cp] (L = SC6F5, M = Mo (1a), W (1b); L = CO, M = Mo (4)) are characterised; crystal structures of 1a and 4 show unusual polydentate coordination of thallium(I) by [Mo(SC6F5)2L2Cp)]- and var. temp. 19F NMR studies, supported by conductivity measurements and cation exchange, indicate restricted rotation of C6F5 groups and reversible decoordination of Tl+ in more polar solvents. {\textcopyright} 1987.",

author = "\{Azalee Wan Abu Bakar\}, W. and Davidson, \{Jack L.\} and Lindsell, \{W. Edward\} and McCullough, \{Kevin J.\} and Muir, \{Kenneth W.\}",

year = "1987",

month = mar,

day = "17",

language = "English",

volume = "322",

pages = "C1--C6",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1",

}

Azalee Wan Abu Bakar, W, Davidson, JL, Lindsell, WE, McCullough, KJ & Muir, KW 1987, 'Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC₆F₅)₂L₂Cp] (L = SC₆F₅ or CO)', Journal of Organometallic Chemistry, vol. 322, no. 1, pp. C1-C6.

Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC₆F₅)₂L₂Cp] (L = SC₆F₅ or CO). / Azalee Wan Abu Bakar, W.; Davidson, Jack L.; Lindsell, W. Edward et al.
In: Journal of Organometallic Chemistry, Vol. 322, No. 1, 17.03.1987, p. C1-C6.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC6F5)2L2Cp] (L = SC6F5 or CO)

AU - Azalee Wan Abu Bakar, W.

AU - Davidson, Jack L.

AU - Lindsell, W. Edward

AU - McCullough, Kevin J.

AU - Muir, Kenneth W.

PY - 1987/3/17

Y1 - 1987/3/17

N2 - New bimetallic complexes [MTl(SC6F5)2L2Cp] (L = SC6F5, M = Mo (1a), W (1b); L = CO, M = Mo (4)) are characterised; crystal structures of 1a and 4 show unusual polydentate coordination of thallium(I) by [Mo(SC6F5)2L2Cp)]- and var. temp. 19F NMR studies, supported by conductivity measurements and cation exchange, indicate restricted rotation of C6F5 groups and reversible decoordination of Tl+ in more polar solvents. © 1987.

AB - New bimetallic complexes [MTl(SC6F5)2L2Cp] (L = SC6F5, M = Mo (1a), W (1b); L = CO, M = Mo (4)) are characterised; crystal structures of 1a and 4 show unusual polydentate coordination of thallium(I) by [Mo(SC6F5)2L2Cp)]- and var. temp. 19F NMR studies, supported by conductivity measurements and cation exchange, indicate restricted rotation of C6F5 groups and reversible decoordination of Tl+ in more polar solvents. © 1987.

UR - https://www.scopus.com/pages/publications/45949117205

M3 - Article

SN - 0022-328X

VL - 322

SP - C1-C6

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC6F5)2L2Cp] (L = SC6F5 or CO)

Abstract

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Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC₆F₅)₂L₂Cp] (L = SC₆F₅ or CO)