TY - JOUR
T1 - Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC6F5)2L2Cp] (L = SC6F5 or CO)
AU - Azalee Wan Abu Bakar, W.
AU - Davidson, Jack L.
AU - Lindsell, W. Edward
AU - McCullough, Kevin J.
AU - Muir, Kenneth W.
PY - 1987/3/17
Y1 - 1987/3/17
N2 - New bimetallic complexes [MTl(SC6F5)2L2Cp] (L = SC6F5, M = Mo (1a), W (1b); L = CO, M = Mo (4)) are characterised; crystal structures of 1a and 4 show unusual polydentate coordination of thallium(I) by [Mo(SC6F5)2L2Cp)]- and var. temp. 19F NMR studies, supported by conductivity measurements and cation exchange, indicate restricted rotation of C6F5 groups and reversible decoordination of Tl+ in more polar solvents. © 1987.
AB - New bimetallic complexes [MTl(SC6F5)2L2Cp] (L = SC6F5, M = Mo (1a), W (1b); L = CO, M = Mo (4)) are characterised; crystal structures of 1a and 4 show unusual polydentate coordination of thallium(I) by [Mo(SC6F5)2L2Cp)]- and var. temp. 19F NMR studies, supported by conductivity measurements and cation exchange, indicate restricted rotation of C6F5 groups and reversible decoordination of Tl+ in more polar solvents. © 1987.
UR - http://www.scopus.com/inward/record.url?scp=45949117205&partnerID=8YFLogxK
M3 - Article
SN - 0022-328X
VL - 322
SP - C1-C6
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -