Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC6F5)2L2Cp] (L = SC6F5 or CO)

W. Azalee Wan Abu Bakar, Jack L. Davidson, W. Edward Lindsell, Kevin J. McCullough, Kenneth W. Muir

Research output: Contribution to journalArticle

Abstract

New bimetallic complexes [MTl(SC6F5)2L2Cp] (L = SC6F5, M = Mo (1a), W (1b); L = CO, M = Mo (4)) are characterised; crystal structures of 1a and 4 show unusual polydentate coordination of thallium(I) by [Mo(SC6F5)2L2Cp)]- and var. temp. 19F NMR studies, supported by conductivity measurements and cation exchange, indicate restricted rotation of C6F5 groups and reversible decoordination of Tl+ in more polar solvents. © 1987.

Original languageEnglish
Pages (from-to)C1-C6
JournalJournal of Organometallic Chemistry
Volume322
Issue number1
Publication statusPublished - 17 Mar 1987

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Tungsten
Molybdenum
Thallium
Carbon Monoxide
Cations
Crystal structure
Nuclear magnetic resonance
Ligands
Derivatives

Cite this

@article{c5b89d422ca0483c821cd5744061ac1d,
title = "Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC6F5)2L2Cp] (L = SC6F5 or CO)",
abstract = "New bimetallic complexes [MTl(SC6F5)2L2Cp] (L = SC6F5, M = Mo (1a), W (1b); L = CO, M = Mo (4)) are characterised; crystal structures of 1a and 4 show unusual polydentate coordination of thallium(I) by [Mo(SC6F5)2L2Cp)]- and var. temp. 19F NMR studies, supported by conductivity measurements and cation exchange, indicate restricted rotation of C6F5 groups and reversible decoordination of Tl+ in more polar solvents. {\circledC} 1987.",
author = "{Azalee Wan Abu Bakar}, W. and Davidson, {Jack L.} and Lindsell, {W. Edward} and McCullough, {Kevin J.} and Muir, {Kenneth W.}",
year = "1987",
month = "3",
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language = "English",
volume = "322",
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journal = "Journal of Organometallic Chemistry",
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Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC6F5)2L2Cp] (L = SC6F5 or CO). / Azalee Wan Abu Bakar, W.; Davidson, Jack L.; Lindsell, W. Edward; McCullough, Kevin J.; Muir, Kenneth W.

In: Journal of Organometallic Chemistry, Vol. 322, No. 1, 17.03.1987, p. C1-C6.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Cyclopentadienyl pentafluorophenylthiolate complexes of molybdenum and tungsten as novel polydentate ligands of thallium(I); dynamic NMR studies and crystal structures of two derivatives [MoTl(SC6F5)2L2Cp] (L = SC6F5 or CO)

AU - Azalee Wan Abu Bakar, W.

AU - Davidson, Jack L.

AU - Lindsell, W. Edward

AU - McCullough, Kevin J.

AU - Muir, Kenneth W.

PY - 1987/3/17

Y1 - 1987/3/17

N2 - New bimetallic complexes [MTl(SC6F5)2L2Cp] (L = SC6F5, M = Mo (1a), W (1b); L = CO, M = Mo (4)) are characterised; crystal structures of 1a and 4 show unusual polydentate coordination of thallium(I) by [Mo(SC6F5)2L2Cp)]- and var. temp. 19F NMR studies, supported by conductivity measurements and cation exchange, indicate restricted rotation of C6F5 groups and reversible decoordination of Tl+ in more polar solvents. © 1987.

AB - New bimetallic complexes [MTl(SC6F5)2L2Cp] (L = SC6F5, M = Mo (1a), W (1b); L = CO, M = Mo (4)) are characterised; crystal structures of 1a and 4 show unusual polydentate coordination of thallium(I) by [Mo(SC6F5)2L2Cp)]- and var. temp. 19F NMR studies, supported by conductivity measurements and cation exchange, indicate restricted rotation of C6F5 groups and reversible decoordination of Tl+ in more polar solvents. © 1987.

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M3 - Article

VL - 322

SP - C1-C6

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 1

ER -