Crystal structure of (E)-1,2-Bis(1,1-dimethyl-2-oxopropyl)diaz-1-ene-1,2-diium-1,2-diolate, the trans-Dimer of 3-Methyl-3-nitrosobutan-2-one

Brian Glover Gowenlock, Kevin James McCullough

Research output: Contribution to journalArticle

Abstract

The solid state structure of (E)-1,2-bis(1,1-dimethyl-2-oxopropyl)diaz-1-ene-1,2-diium-1,2-diolate, (3a), the trans-dimer of 3-methyl-3-nitrosobutan-2-one, has been determined by X-ray crystallographic analysis; subsequent comparison of the observed geometrical parameters for 3a with the literature values for eleven other trans or (E)-dimers suggests that there is no correlation between the N - N distances in these dimers and their respective rates of dissociation to monomer in solution.

Original languageEnglish
Pages (from-to)270-271
Number of pages2
JournalJournal of Chemical Research, Synopses
Issue number8
DOIs
Publication statusPublished - 1997

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Dimers
Crystal structure
Monomers
X rays

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title = "Crystal structure of (E)-1,2-Bis(1,1-dimethyl-2-oxopropyl)diaz-1-ene-1,2-diium-1,2-diolate, the trans-Dimer of 3-Methyl-3-nitrosobutan-2-one",
abstract = "The solid state structure of (E)-1,2-bis(1,1-dimethyl-2-oxopropyl)diaz-1-ene-1,2-diium-1,2-diolate, (3a), the trans-dimer of 3-methyl-3-nitrosobutan-2-one, has been determined by X-ray crystallographic analysis; subsequent comparison of the observed geometrical parameters for 3a with the literature values for eleven other trans or (E)-dimers suggests that there is no correlation between the N - N distances in these dimers and their respective rates of dissociation to monomer in solution.",
author = "Gowenlock, {Brian Glover} and McCullough, {Kevin James}",
year = "1997",
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language = "English",
pages = "270--271",
journal = "Journal of Chemical Research, Synopses",
issn = "0308-2342",
publisher = "Science Reviews Ltd",
number = "8",

}

Crystal structure of (E)-1,2-Bis(1,1-dimethyl-2-oxopropyl)diaz-1-ene-1,2-diium-1,2-diolate, the trans-Dimer of 3-Methyl-3-nitrosobutan-2-one. / Gowenlock, Brian Glover; McCullough, Kevin James.

In: Journal of Chemical Research, Synopses, No. 8, 1997, p. 270-271.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Crystal structure of (E)-1,2-Bis(1,1-dimethyl-2-oxopropyl)diaz-1-ene-1,2-diium-1,2-diolate, the trans-Dimer of 3-Methyl-3-nitrosobutan-2-one

AU - Gowenlock, Brian Glover

AU - McCullough, Kevin James

PY - 1997

Y1 - 1997

N2 - The solid state structure of (E)-1,2-bis(1,1-dimethyl-2-oxopropyl)diaz-1-ene-1,2-diium-1,2-diolate, (3a), the trans-dimer of 3-methyl-3-nitrosobutan-2-one, has been determined by X-ray crystallographic analysis; subsequent comparison of the observed geometrical parameters for 3a with the literature values for eleven other trans or (E)-dimers suggests that there is no correlation between the N - N distances in these dimers and their respective rates of dissociation to monomer in solution.

AB - The solid state structure of (E)-1,2-bis(1,1-dimethyl-2-oxopropyl)diaz-1-ene-1,2-diium-1,2-diolate, (3a), the trans-dimer of 3-methyl-3-nitrosobutan-2-one, has been determined by X-ray crystallographic analysis; subsequent comparison of the observed geometrical parameters for 3a with the literature values for eleven other trans or (E)-dimers suggests that there is no correlation between the N - N distances in these dimers and their respective rates of dissociation to monomer in solution.

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