Crystal structure of 1-heptafluorotolyl-closo-1,2-dicarbadodecaborane

James D. Watson, Amanda Benton, Hugo Tricas, Georgina Margaret Rosair, Alan Jeffrey Welch

Research output: Contribution to journalArticle

22 Downloads (Pure)

Abstract

The mol­ecular structure of the title compound 1-(2′,3′,5′,6′-tetra­fluoro-4′-trifluoro­methyl­phen­yl)-closo-1,2-dicarbadodeca­borane, C9H11B10F7, features an intra­molecular ortho-F⋯H2 hydrogen bond [2.11 (2) Å], which is responsible for an orientation of the hepta­fluoro­tolyl substituent in which the plane of the aryl ring nearly eclipses the C1—C2 cage connectivity.
Original languageEnglish
Pages (from-to)512-515
Number of pages4
JournalActa Crystallographica Section E: Crystallographic Communications
Volume75
Issue number4
Early online date29 Mar 2019
DOIs
Publication statusPublished - Apr 2019

Keywords

  • carborane
  • crystal structure
  • intramolecular F...H hydrogen-bond

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Fingerprint Dive into the research topics of 'Crystal structure of 1-heptafluorotolyl-closo-1,2-dicarbadodecaborane'. Together they form a unique fingerprint.

Cite this