Abstract
In the title compound, (2,2′-bipyridine-κ2 N,N′)bis(2-methoxyethyl xanthato-κS)zinc(II), [Zn(C4H7O2S2)2(C10H8N2)], the ZnII ion is coordinated to two N atoms of the 2,2′-bipyridine ligand and two S atoms from two 2-methoxyethyl xanthate ligands. The ZnII ion lies on a crystallographic twofold rotation axis and has distorted tetrahedral coordination geometry. In the crystal, molecules are linked by weak C - H⋯O hydrogen bonds, forming supramolecular chains propagating along the a-axis direction. Weak intramolecular C - H⋯S hydrogen bonds are also observed. The intermolecular contacts in the crystal were further analysed using Hirshfield surface analysis, which indicates that the most significant contacts are H⋯H (36.3%), followed by S⋯H/H⋯S (24.7%), C⋯H/H⋯C (15.1%), O⋯H/H⋯O (14.4%), N⋯H/H⋯N (4.1%) and C⋯C (2.9%).
Original language | English |
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Pages (from-to) | 1857-1860 |
Number of pages | 4 |
Journal | Acta Crystallographica Section E: Crystallographic Communications |
Volume | 75 |
Issue number | 12 |
Early online date | 12 Nov 2019 |
DOIs | |
Publication status | Published - Dec 2019 |
Keywords
- 2,2′-bipyridine
- crystal structure
- Hirshfeld surface
- xanthate
- zinc(II)
ASJC Scopus subject areas
- General Chemistry
- General Materials Science
- Condensed Matter Physics