Crystal engineering with heteroboranes. III. 2-Carboxy-1-methoxy-methyl-1,2-dicarba-closo-dodecaborane(12)

Ulaganathan Venkatasubramanian; David Ellis; Georgina M. Rosair; Alan J. Welch

doi:10.1107/S0108270103019048

Crystal engineering with heteroboranes. III. 2-Carboxy-1-methoxy-methyl-1,2-dicarba-closo-dodecaborane(12)

Ulaganathan Venkatasubramanian
, David Ellis
, Georgina M. Rosair
, Alan J. Welch

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The title compound, 1-CH₂OCH₃-2-COOH-1,2-closo-C ₂B₁₀H₁₀ or C₅H₁₆B ₁₀O₃, forms a discrete centrosymmetric tetramer, via hydrogen bonding, involving two inner and two outer carborane molecules. One conventional eight-membered hydrogen-bonded ring [graph set R₂²(8)] is formed between two carboxylic acid groups of the inner carboranes. This interaction is then supplemented by an open finite hydrogen bond (graph set D) between the ether O atom of the inner carborane and the carboxylic acid H atom of the outer carborane.

Original language	English
Pages (from-to)	o586-o588
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	59
Issue number	10
DOIs	https://doi.org/10.1107/S0108270103019048
Publication status	Published - Oct 2003

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title = "Crystal engineering with heteroboranes. III. 2-Carboxy-1-methoxy-methyl-1,2-dicarba-closo-dodecaborane(12)",

abstract = "The title compound, 1-CH2OCH3-2-COOH-1,2-closo-C 2B10H10 or C5H16B 10O3, forms a discrete centrosymmetric tetramer, via hydrogen bonding, involving two inner and two outer carborane molecules. One conventional eight-membered hydrogen-bonded ring [graph set R22(8)] is formed between two carboxylic acid groups of the inner carboranes. This interaction is then supplemented by an open finite hydrogen bond (graph set D) between the ether O atom of the inner carborane and the carboxylic acid H atom of the outer carborane.",

author = "Ulaganathan Venkatasubramanian and David Ellis and Rosair, \{Georgina M.\} and Welch, \{Alan J.\}",

year = "2003",

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doi = "10.1107/S0108270103019048",

language = "English",

volume = "59",

pages = "o586--o588",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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publisher = "International Union of Crystallography",

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T1 - Crystal engineering with heteroboranes. III. 2-Carboxy-1-methoxy-methyl-1,2-dicarba-closo-dodecaborane(12)

AU - Venkatasubramanian, Ulaganathan

AU - Ellis, David

AU - Rosair, Georgina M.

AU - Welch, Alan J.

PY - 2003/10

Y1 - 2003/10

N2 - The title compound, 1-CH2OCH3-2-COOH-1,2-closo-C 2B10H10 or C5H16B 10O3, forms a discrete centrosymmetric tetramer, via hydrogen bonding, involving two inner and two outer carborane molecules. One conventional eight-membered hydrogen-bonded ring [graph set R22(8)] is formed between two carboxylic acid groups of the inner carboranes. This interaction is then supplemented by an open finite hydrogen bond (graph set D) between the ether O atom of the inner carborane and the carboxylic acid H atom of the outer carborane.

AB - The title compound, 1-CH2OCH3-2-COOH-1,2-closo-C 2B10H10 or C5H16B 10O3, forms a discrete centrosymmetric tetramer, via hydrogen bonding, involving two inner and two outer carborane molecules. One conventional eight-membered hydrogen-bonded ring [graph set R22(8)] is formed between two carboxylic acid groups of the inner carboranes. This interaction is then supplemented by an open finite hydrogen bond (graph set D) between the ether O atom of the inner carborane and the carboxylic acid H atom of the outer carborane.

UR - https://www.scopus.com/pages/publications/0242412203

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DO - 10.1107/S0108270103019048

M3 - Article

SN - 1600-5759

VL - 59

SP - o586-o588

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 10

ER -

Crystal engineering with heteroboranes. III. 2-Carboxy-1-methoxy-methyl-1,2-dicarba-closo-dodecaborane(12)

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